Published November 1984 | Version v1
Journal article

Mossbauer, infrared and magnetic characterization of iron/cobalt species in cage structure alumino-silicates (Zeolites)

  • 1. The Pennsylvania State University, University Park, PA 16802

Description

Magnetic, Mossbauer, and I.R. studies on S.P. (superparamagnetic) or M.D. (multidomain) particles of Fe and Co species dispersed in cage structure aluminosilicates in relation to syngas (CO+H2) Fischer-Tropsch conversion are reported. The difference in the catalytic activity of such species has been shown to depend upon their degree of dispersion. The carbonyl impregnation gave ultra-fine S.P. Fe3O4, whereas the nitrate impregnation gave M.D. Fe3O4 or omicron-Fe2O3. The active Fe5C2 component was converted to Fe3C during the above reaction

Additional details

Publishing Information

Journal Title
Mater. Res. Bull.
Journal Volume
19
Journal Issue
11
Series
Mater. Res. Bull.
Journal Page Range
1411-1425
ISSN
0025-5408