Published January 1989 | Version v1
Journal article Metadata-only

Synthesis and properties of mixed-ligand molybdenum(3) exchange clusters

Creators

  • 1. Moskovskij Gosudarstvennyj Univ., Moscow (USSR)

Description

Synthesis of mixed-ligand binuclear Mo3+ complexes, revealing the properties of exchange clusters, was accomplished: di-μ-chloro-μ-bromohexachloromolybdates of tetrabutylammonium, ammonium, tetramethylammonium of (R4N)3MO2Cl8Br composition (where R=Bu, Me, H) as well as di-μ-chloto-μ-isothiocianatohexachlorodimolybdates(3) of tetrabutylammonium and tetramethylammonium of (R4N)3MO2Cl8(NCS) composition (where R=Bu,Me). Their electron and IR spectra, thermomagnetic properties were studied; X-ray phase analysis was conducted

Additional details

Additional titles

Original title (Russian)
Синтез и свойства смешаннолигандных обменных кластеров молибдена(3)

Publishing Information

Journal Title
Zhurnal Neorganicheskoj Khimii
Journal Volume
34
Journal Issue
1
Series
Zh. Neorg. Khim.
Journal Page Range
83-87
ISSN
0044-457X
CODEN
ZNOKA

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
20044097
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
AMMONIUM COMPOUNDS; BROMIDES; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; CHEMICAL REACTION YIELD; CHLORIDES; INFRARED SPECTRA; LATTICE PARAMETERS; MAGNETIC SUSCEPTIBILITY; MOLECULAR STRUCTURE; MOLYBDENUM COMPLEXES; QUATERNARY COMPOUNDS; THIOCYANATES; ULTRAVIOLET SPECTRA
Descriptors DEC
AMINES; ANTITHYROID DRUGS; BROMINE COMPOUNDS; CARBONIC ACID DERIVATIVES; CHLORINE COMPOUNDS; COMPLEXES; DRUGS; HALIDES; HALOGEN COMPOUNDS; MAGNETIC PROPERTIES; ORGANIC COMPOUNDS; ORGANIC SULFUR COMPOUNDS; PHYSICAL PROPERTIES; SPECTRA; SYNTHESIS; TRANSITION ELEMENT COMPLEXES