Measurements of the density and viscosity of binary mixtures of (hyper-branched polymer, B-H2004 + 1-butanol, or 1-hexanol, or 1-octanol, or methyl tert-butyl ether)
- 1. Physical Chemistry Division, Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw (Poland)
Description
Density and viscosity were determined for binary mixtures of {hyper-branched polymer, Boltorn H2004 (B-H2004) + 1-alcohol (1-butanol, 1-hexanol, and 1-octanol)} at T = (298.15, 308.15, 318.15, 328.15, and 338.15) K and of {B-H2004 + methyl tert-butyl ether (MTBE)} at T = (298.15, 308.15, and 318.15) K and ambient pressure. The temperature dependence of density and viscosity is described by linear regression and by the Vogel-Fucher-Tammann equation, respectively. Excess volumes for the system {B-H2004 + MTBE} are presented as a function of mass fraction. Viscosity deviations were calculated and correlated by the Redlich-Kister polynomial expansions using also the mass fractions. The polynomial correlations describe the variation of viscosity with composition. A qualitative discussion on these quantities in terms of molecular interactions is reported.
Availability note (English)
Available from http://dx.doi.org/10.1016/j.jct.2009.12.005Additional details
Identifiers
- DOI
- 10.1016/j.jct.2009.12.005;
- PII
- S0021-9614(09)00301-2;
Publishing Information
- Journal Title
- Journal of Chemical Thermodynamics
- Journal Volume
- 42
- Journal Issue
- 5
- Journal Page Range
- p. 651-658
- ISSN
- 0021-9614
- CODEN
- JCTDAF
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 41076872
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- BINARY MIXTURES; BUTANOLS; BUTYL ETHER; CORRELATIONS; DENSITY; EQUATIONS; EXPANSION; INTERACTIONS; POLYMERS; POLYNOMIALS; TEMPERATURE DEPENDENCE; TEMPERATURE RANGE 0273-0400 K; VISCOSITY
- Descriptors DEC
- ALCOHOLS; DISPERSIONS; ETHERS; FUNCTIONS; HYDROXY COMPOUNDS; MIXTURES; ORGANIC COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; TEMPERATURE RANGE
Optional Information
- Copyright
- Copyright (c) 2010 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.