Published May 2010 | Version v1
Journal article

Measurements of the density and viscosity of binary mixtures of (hyper-branched polymer, B-H2004 + 1-butanol, or 1-hexanol, or 1-octanol, or methyl tert-butyl ether)

  • 1. Physical Chemistry Division, Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw (Poland)

Description

Density and viscosity were determined for binary mixtures of {hyper-branched polymer, Boltorn H2004 (B-H2004) + 1-alcohol (1-butanol, 1-hexanol, and 1-octanol)} at T = (298.15, 308.15, 318.15, 328.15, and 338.15) K and of {B-H2004 + methyl tert-butyl ether (MTBE)} at T = (298.15, 308.15, and 318.15) K and ambient pressure. The temperature dependence of density and viscosity is described by linear regression and by the Vogel-Fucher-Tammann equation, respectively. Excess volumes for the system {B-H2004 + MTBE} are presented as a function of mass fraction. Viscosity deviations were calculated and correlated by the Redlich-Kister polynomial expansions using also the mass fractions. The polynomial correlations describe the variation of viscosity with composition. A qualitative discussion on these quantities in terms of molecular interactions is reported.

Availability note (English)

Available from http://dx.doi.org/10.1016/j.jct.2009.12.005

Additional details

Identifiers

DOI
10.1016/j.jct.2009.12.005;
PII
S0021-9614(09)00301-2;

Publishing Information

Journal Title
Journal of Chemical Thermodynamics
Journal Volume
42
Journal Issue
5
Journal Page Range
p. 651-658
ISSN
0021-9614
CODEN
JCTDAF

Optional Information

Copyright
Copyright (c) 2010 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.