Published April 2008 | Version v1
Journal article

Excess molar volumes of (octane + benzene, or toluene, or 1,3-xylene, or 1,3,5-trimethylbenzene) at temperatures between (298.15 and 328.15) K

  • 1. E. Hala Laboratory of Thermodynamics, Institute of Chemical Process Fundamentals of the ASCR, v.v.i, 165 02 Prague 6 (Czech Republic)

Description

The densities of (octane + benzene, or toluene, or 1,3-xylene, or 1,3,5-trimethylbenzene) were measured at temperatures (298.15, 308.15, 318.15, and 328.15) K by means of a vibrating-tube densimeter. The excess molar volumes VmE calculated from the density data provide the temperature dependence of VmE in the temperature range of (298 to 328) K. The VmE results were correlated using the fourth-order Redlich-Kister equation, with the maximum likelihood principle being applied for the determination of the adjustable parameters. It was found that the values of VmE are not very much dependent on temperature and in all cases decrease with the number of methyl groups on benzene ring of the alkylbenzene

Availability note (English)

Available from http://dx.doi.org/10.1016/j.jct.2007.10.010

Additional details

Identifiers

DOI
10.1016/j.jct.2007.10.010;
PII
S0021-9614(07)00206-6;

Publishing Information

Journal Title
Journal of Chemical Thermodynamics
Journal Volume
40
Journal Issue
4
Journal Page Range
p. 671-676
ISSN
0021-9614
CODEN
JCTDAF

Optional Information

Copyright
Copyright (c) 2007 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.