Published April 2008
| Version v1
Journal article
Excess molar volumes of (octane + benzene, or toluene, or 1,3-xylene, or 1,3,5-trimethylbenzene) at temperatures between (298.15 and 328.15) K
Creators
- 1. E. Hala Laboratory of Thermodynamics, Institute of Chemical Process Fundamentals of the ASCR, v.v.i, 165 02 Prague 6 (Czech Republic)
Description
The densities of (octane + benzene, or toluene, or 1,3-xylene, or 1,3,5-trimethylbenzene) were measured at temperatures (298.15, 308.15, 318.15, and 328.15) K by means of a vibrating-tube densimeter. The excess molar volumes VmE calculated from the density data provide the temperature dependence of VmE in the temperature range of (298 to 328) K. The VmE results were correlated using the fourth-order Redlich-Kister equation, with the maximum likelihood principle being applied for the determination of the adjustable parameters. It was found that the values of VmE are not very much dependent on temperature and in all cases decrease with the number of methyl groups on benzene ring of the alkylbenzene
Availability note (English)
Available from http://dx.doi.org/10.1016/j.jct.2007.10.010Additional details
Identifiers
- DOI
- 10.1016/j.jct.2007.10.010;
- PII
- S0021-9614(07)00206-6;
Publishing Information
- Journal Title
- Journal of Chemical Thermodynamics
- Journal Volume
- 40
- Journal Issue
- 4
- Journal Page Range
- p. 671-676
- ISSN
- 0021-9614
- CODEN
- JCTDAF
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 40016581
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- BENZENE; BINARY MIXTURES; DENSIMETERS; DENSITY; EQUATIONS; MAXIMUM-LIKELIHOOD FIT; MESITYLENE; OCTANE; TEMPERATURE DEPENDENCE; TEMPERATURE RANGE 0273-0400 K; TOLUENE; XYLENES
- Descriptors DEC
- ALKANES; ALKYLATED AROMATICS; AROMATICS; DISPERSIONS; HYDROCARBONS; MATHEMATICAL SOLUTIONS; MEASURING INSTRUMENTS; MIXTURES; NUMERICAL SOLUTION; ORGANIC COMPOUNDS; PHYSICAL PROPERTIES; TEMPERATURE RANGE
Optional Information
- Copyright
- Copyright (c) 2007 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.