Stimuli-responsive photoluminescence soft hybrid microgel particles: synthesis and characterizations

Stimuli-responsive (pH and temperature sensitive) photoluminescence hybrid particles are prepared using oppositely charged cationic microgels of Poly(N-isopropyl polyacrylamide) (PNIPAm) and anionic cadmium sulfide (CdS) quantum dots (QDs). A facile synthetic strategy such as in situ/post incorporation of QDs along with pH tuneable electrostatic interactions is optimized to obtain hybrid microgels with maximum photoluminescence. Transmission electron microscope (TEM), fluorescence spectroscopy and dynamic light scattering (DLS) methods are used for characterizing the synthesized hybrid particles. TEM studies directly confirm the successful loading of QDs onto microgels whereas fluorescence spectroscopy reveals higher photo luminosity of the hybrid microgels prepared via in situ compared to post incorporation method. The pH-dependent photoluminescence supported by temperature-dependent swelling studies using DLS suggest that the hybrid microgels prepared at low pH have greater fluorescence with less thermoresponsivity and these behaviors follow an opposite trend with increasing pH. Further, these results are compared with the hybrid microgels prepared using similar charged anionic microgels and anionic quantum dots under same experimental condition (via in situ) and suggest that maximum photoluminescence can be achieved only through oppositely charged species. (paper)