Treatment of PFAS-containing landfill leachate using an enhanced contact plasma reactor

Highlights: • PFAS concentrations ranged from 10² to 10⁵ ng/L in three leachate samples. • Plasma treatment removed the PFOA+PFOS concentration to • Greater than 99.9% of the long-chain PFAAs were removed after plasma treatment. • Plasma treatment efficiency was not compromised by the presence of co-contaminants. • Addition of cationic surfactant (CTAB) increases the removal of short-chain PFAAs. A bench-scale plasma reactor was used to degrade poly- and perfluoroalkyl substances (PFAS) in landfill leachate samples obtained from three different locations. In the leachate samples before treatment, five long-chain, six short-chain perfluoroalkyl acids (PFAAs) and eight PFAA precursors were detected in a wide concentration range (~10² to 10⁵ ng/L; total oxidizable precursors (TOP) ~10⁶ ng/L). The concentration of perfluorooctane sulfonate (PFOS) plus perfluorooctanoic acid (PFOA) ranged between 2000 and 3000 ng/L. Plasma-based water treatment of 500 mL samples resulted in faster removal rates for longer-chain than shorter chain length PFAAs. Both PFOS and PFOA were removed to below United States Environmental Protection Agency's (USEPA's) health advisory concentration level (HAL) concentrations (99.9% and 10–99.9%, respectively. The removal rate constant (k_PFOA+PFOS) for combined PFOA and PFOS ranged between 0.20 and 0.34 min^-1. Overall, 60 ± 2% of the TOP concentration and 34 ± 2% of the TOC were removed. No effect of non-PFAS co-contaminants (e.g., total initial organic carbon concentration ~2000 mg/L) on the degradation efficiency was observed. Short-chain PFAA removal efficacy was enhanced by adding a cationic surfactant (cetrimonium bromide). Overall, the results indicate that plasma-based technology may be a viable technology for the treatment of PFAS-contaminated landfill leachates.