Computation of thermodynamic plasma properties: A simplified approach
- 1. Chemistry Dept., University of Bari, via Orabona 4, 70125 Bari (Italy)
- 2. CNR-IMIP Bari, via Amendola, 122/D 70125 Bari (Italy)
Description
An approximate method for calculating the electronic partition functions of atomic systems is reported. The method is based on the idea of combining a multitude of atomic energy levels into two or three grouped levels. Dimensionless formulation suitable for practical calculations is presented. Application to real systems shows that two grouped levels are enough to model hydrogen-like and noble gas atoms, whereas three grouped levels are required to describe atoms with low lying excited states. Two methods for the calculation of degeneracy and energy values of the grouped levels are investigated. Representative mono-atomic LTE plasma properties calculations are reported. The results agree with accurate computations using partition functions that include several thousands energy levels.
Availability note (English)
Available from http://dx.doi.org/10.1016/j.sab.2010.05.002Additional details
Identifiers
- DOI
- 10.1016/j.sab.2010.05.002;
- PII
- S0584-8547(10)00133-3;
Publishing Information
- Journal Title
- Spectrochimica Acta. Part B, Atomic Spectroscopy
- Journal Volume
- 65
- Journal Issue
- 8
- Journal Page Range
- p. 603-615
- ISSN
- 0584-8547
- CODEN
- SAASBH
Conference
- Title
- 5. Euro-Mediterranean symposium on laser induced breakdown spectroscopy
- Acronym
- EMSLIBS 2009
- Dates
- 28 Sep - 1 Oct 2009
- Place
- Rome (Italy)
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 42043054
- Subject category
- S71: CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Resource subtype / Literary indicator
- Conference
- Descriptors DEI
- APPROXIMATIONS; EMISSION SPECTROSCOPY; EXCITED STATES; PARTITION FUNCTIONS; PLASMA; RARE GASES
- Descriptors DEC
- CALCULATION METHODS; ELEMENTS; ENERGY LEVELS; FLUIDS; FUNCTIONS; GASES; NONMETALS; SPECTROSCOPY
Optional Information
- Copyright
- Copyright (c) 2010 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.