Published August 2010 | Version v1
Journal article

Computation of thermodynamic plasma properties: A simplified approach

  • 1. Chemistry Dept., University of Bari, via Orabona 4, 70125 Bari (Italy)
  • 2. CNR-IMIP Bari, via Amendola, 122/D 70125 Bari (Italy)

Description

An approximate method for calculating the electronic partition functions of atomic systems is reported. The method is based on the idea of combining a multitude of atomic energy levels into two or three grouped levels. Dimensionless formulation suitable for practical calculations is presented. Application to real systems shows that two grouped levels are enough to model hydrogen-like and noble gas atoms, whereas three grouped levels are required to describe atoms with low lying excited states. Two methods for the calculation of degeneracy and energy values of the grouped levels are investigated. Representative mono-atomic LTE plasma properties calculations are reported. The results agree with accurate computations using partition functions that include several thousands energy levels.

Availability note (English)

Available from http://dx.doi.org/10.1016/j.sab.2010.05.002

Additional details

Identifiers

DOI
10.1016/j.sab.2010.05.002;
PII
S0584-8547(10)00133-3;

Publishing Information

Journal Title
Spectrochimica Acta. Part B, Atomic Spectroscopy
Journal Volume
65
Journal Issue
8
Journal Page Range
p. 603-615
ISSN
0584-8547
CODEN
SAASBH

Conference

Title
5. Euro-Mediterranean symposium on laser induced breakdown spectroscopy
Acronym
EMSLIBS 2009
Dates
28 Sep - 1 Oct 2009
Place
Rome (Italy)

INIS

Country of Publication
Netherlands
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
42043054
Subject category
S71: CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Resource subtype / Literary indicator
Conference
Descriptors DEI
APPROXIMATIONS; EMISSION SPECTROSCOPY; EXCITED STATES; PARTITION FUNCTIONS; PLASMA; RARE GASES
Descriptors DEC
CALCULATION METHODS; ELEMENTS; ENERGY LEVELS; FLUIDS; FUNCTIONS; GASES; NONMETALS; SPECTROSCOPY

Optional Information

Copyright
Copyright (c) 2010 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.