Published May 20, 1981
| Version v1
Journal article
Transition-metal nitro-nitrosyl redox couple: catalytic oxidation of olefins to ketones
Description
A new nitroso-nitrosyl redox couple based on the readily prepared complex bis(acetonitrile)chloronitropalladium(II) is reported which catalytically air oxidizes olefines to ketones. Results of 18O labelling mechanistic studies are included, and spectroscopic evidence for an intermediate involved in oxygen-atom transfer by a nitro group is presented. The effects of olefin substituents were also investigated
Additional details
Publishing Information
- Journal Title
- J. Am. Chem. Soc.
- Journal Volume
- 103
- Journal Issue
- 10
- Series
- J. Am. Chem. Soc.
- Journal Page Range
- 2894-2896
- ISSN
- 0002-7863
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 13647249
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ALKENES; CATALYSIS; CHEMICAL PREPARATION; CHLORINE COMPOUNDS; KETONES; LABELLED COMPOUNDS; NITRO COMPOUNDS; ORGANOMETALLIC COMPOUNDS; OXIDATION; OXYGEN 18; PALLADIUM COMPLEXES; REACTION KINETICS
- Descriptors DEC
- CHEMICAL REACTIONS; COMPLEXES; EVEN-EVEN NUCLEI; HALOGEN COMPOUNDS; HYDROCARBONS; ISOTOPES; KINETICS; LIGHT NUCLEI; NUCLEI; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; OXYGEN ISOTOPES; STABLE ISOTOPES; SYNTHESIS; TRANSITION ELEMENT COMPLEXES