Published March 2009 | Version v1
Journal article Metadata-only

Crystal structure of [Mn(1,10-C12H8N2)3](B6H7)2

Creators

  • 1. Inst. Neorganicheskoj Khimii im. A.V. Nikolaeva SO RAN, Novosibirsk (Russian Federation)

Description

New compound [MnII(Phen)3]2+(B6H7)2- was synthesized and its crystal structure was studied by X-ray structure analysis at 100 K. Crystallographic data are: C36H38B12N6Mn, M=739.39, triclinic system, sp. gr. P 1-bar, lattice parameters: a=10.3131(3), b=13.4839(4), c=15.1132(4) A; α=97.696(1), β=108.324(1), γ=102.211(1) Deg, V=1903.9(1) A3, Z=2, dcal=1.290 g/cm3. The structure was solved by the direct and Fourier methods, and refined by full-matrix MLS in anisotropic (isotropic for hydrogen atoms) approximation to the final factor R1=0.036 for 10169 Ihkl≥2σI. The structure contains two crystallographically different anions

Abstract (Russian)

@@@@@@@@@@@@@ @@@@@ @@@@@@@@@@ [MnII(Phen)3]2+(B6H7)2-, @@@@@@@ @@@ @@@ 100 @ @@@@@@@@@@@ @@@ @@@@@@@@@@@@@@@ @@@@@@@@@. @@@@@@@@@@@@@@@@@@@@ @@@@@@: C36H38B12N6Mn, @=739.39, @@@@@@@ @@@@@@@@@@, @@. @@. @ 1-bar, @@@@@@@@@ @@@@@@@@@@@@ @@@@@@: @=10.3131(3), b=13.4839(4), @=15.1132(4) @; α=97.696(1), β=108.324(1), γ=102.211(1) @@@@, V=1903.9(1) @3, Z=2, d@@@=1.290 @/@@3. @@@@@@@@@ @@@@@@@@@@@@ @@@@@@ @ @@@@@ @@@@@@@@ @ @@@@@@@@ @@@@@@@@@@@@@@ @@@ @ @@@@@@@@@@@@ (@@@@@@@@@@ @@@ @@@@@@ @@@@@@@@) @@@@@@@@@@@ @@ @@@@@@@@@@@@@@@ @@@@@@@ R1=0.036 @@@ 10169 Ihkl≥2σI. @@@@@@@@@ @@@@@@@@ @@@ @@@@@@@@@@@@@@@@@@@ @@@@@@ @@@@@@

Additional details

Additional titles

Original title (Russian)
Кристаллическая структура [Мн(1,10-C

Publishing Information

Journal Title
Zhurnal Strukturnoj Khimii
Journal Volume
50
Journal Issue
2
Journal Page Range
p. 381-385
ISSN
0136-7463
CODEN
ZSTKAI

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
41055891
Subject category
S36: MATERIALS SCIENCE; S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ATOMIC CLUSTERS; BORANES; CHEMICAL PREPARATION; FOURIER ANALYSIS; LATTICE PARAMETERS; LEAST SQUARE FIT; MANGANESE COMPOUNDS; MONOCRYSTALS; PHENANTHROLINES; TEMPERATURE RANGE 0065-0273 K; TRICLINIC LATTICES; X-RAY DIFFRACTION
Descriptors DEC
AROMATICS; AZAARENES; BORON COMPOUNDS; COHERENT SCATTERING; CRYSTAL LATTICES; CRYSTAL STRUCTURE; CRYSTALS; DIFFRACTION; HETEROCYCLIC COMPOUNDS; HYDRIDES; HYDROGEN COMPOUNDS; MATHEMATICAL SOLUTIONS; MAXIMUM-LIKELIHOOD FIT; NUMERICAL SOLUTION; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; SCATTERING; SYNTHESIS; TEMPERATURE RANGE; TRANSITION ELEMENT COMPOUNDS

Optional Information

Notes
14 refs., 2 figs., 3 tabs.