Published 1993 | Version v1
Journal article Metadata-only

Interaction of molybdenum (5) and iron (3) in hydrochloric acid aqueous solutions

Creators

  • 1. Kazanskij Gosudarstvennyj Univ., Kazan (Russian Federation)

Description

Redox interaction in the system Mo(5) and Fe(3) was studied. The possibility of quantitative (99.84%) reduction of molybdenum (4) by iron (2) in the medium of 11.0-13.0 mol/l HCl is shown. Parameters of accumulation and concentrational stability constants of chloride complexes of Fe (3) in the range of HCl concentrations of 0-11.0 mol/l are determined. Parameters of accumulation and concentrational stability constants of heteronuclear complex forms that occur in the absence redox interaction are calculated, as well

Additional details

Additional titles

Original title (Russian)
Взаимодействие молибдена (5) и железа (3) в солянокислых водных растворах

Publishing Information

Journal Title
Izvestiya Vysshikh Uchebnykh Zavedenij, Khimiya i Khimicheskaya Tekhnologiya
Journal Volume
36
Journal Issue
5
Journal Page Range
p. 13-18.
ISSN
0579-2991
CODEN
IVUKAR

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
25027431
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
AQUEOUS SOLUTIONS; CONCENTRATION RATIO; HYDROCHLORIC ACID; MOLYBDENUM COMPLEXES; MOLYBDENUM COMPOUNDS; OPACITY; OXIDATION; REDOX POTENTIAL; REDUCTION; STABILITY
Descriptors DEC
CHEMICAL REACTIONS; CHLORINE COMPOUNDS; COMPLEXES; DISPERSIONS; HALOGEN COMPOUNDS; HOMOGENEOUS MIXTURES; HYDROGEN COMPOUNDS; INORGANIC ACIDS; INORGANIC COMPOUNDS; MIXTURES; OPTICAL PROPERTIES; PHYSICAL PROPERTIES; SOLUTIONS; TRANSITION ELEMENT COMPLEXES; TRANSITION ELEMENT COMPOUNDS