High-entropy bulk metallic glasses as promising magnetic refrigerants

In this paper, the Ho₂₀Er₂₀Co₂₀Al₂₀RE₂₀ (RE = Gd, Dy, and Tm) high-entropy bulk metallic glasses (HE-BMGs) with good magnetocaloric properties are fabricated successfully. The HE-BMGs exhibit a second-order magnetic phase transition. The peak of magnetic entropy change (ΔS_M^pk) and refrigerant capacity (RC) reaches 15.0 J kg⁻¹ K⁻¹ and 627 J kg⁻¹ at 5 T, respectively, which is larger than most rare earth based BMGs. The heterogeneous nature of glasses also contributes to the large ΔS_M^pk and RC. In addition, the magnetic ordering temperature, ΔS_M^pk and RC can be widely tuned by alloying different rare earth elements. These results suggest that the HE-BMGs are promising magnetic refrigerant at low temperatures