On the thermal stability of europium- and gadolinium glycinates
- 1. Belorusskij Tekhnologicheskij Inst., Minsk
- 2. Belorusskij Gosudarstvennyj Univ., Minsk
Description
Thermal stability of gadolinium and europium glycinates of the 1:1, 1:2, 1:3 composition, prepared in the solid state for the first time is studied. Thermal decomposition of complexes follows the dehydration process. On the basis of derivatography data an assumption is made about a double nature of water bond in REE complexes with glycine Dehydration is accompanied by the alte ations in the crystal lattice of Cd complexes with glycinate./ Thermal stability of europium glycinates is higher than that/ of gadolinium and depends upon the stoichiometric composition/ of complexes. On the basis of IR spectra data the assumption/ is accompanied by the alterations in the crystal lattice of Cd complexes with glycinate. Thermal stability of europium glycinates is higher than that of gadolinium and depends upon the stoichiometric composition of complexes. On the basis of IR spectra data the assumption is made about the possible glycine coordination with metals
Additional details
Additional titles
- Original title (Russian)
- О термической устойчивости глицинатов европия и гадолиния
Publishing Information
- Journal Title
- Zh. Obshch. Khim.
- Journal Volume
- 50
- Journal Issue
- 3
- Series
- Zh. Obshch. Khim.
- Journal Page Range
- 481-485
- ISSN
- 0044-460X
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- USSR
- INIS RN
- 11569082
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CHEMICAL COMPOSITION; CHEMICAL PREPARATION; EUROPIUM COMPLEXES; GADOLINIUM COMPLEXES; GLYCINE; HYDRATES; INFRARED SPECTRA; PYROLYSIS; X-RAY DIFFRACTION
- Descriptors DEC
- AMINO ACIDS; CARBOXYLIC ACIDS; CHEMICAL REACTIONS; COHERENT SCATTERING; COMPLEXES; DECOMPOSITION; DIFFRACTION; ORGANIC ACIDS; ORGANIC COMPOUNDS; RARE EARTH COMPLEXES; SCATTERING; SPECTRA; SYNTHESIS
Optional Information
- Notes
- For English translation see the journal Journal of General Chemistry of the USSR (USA).