Published 2014 | Version v1
Miscellaneous

The effects of Ce and Y DOPPING in a Ca2MnReO6 double perovskite

  • 1. Universidade Federal do Espírito Santo, Vitoria, ES (Brazil)

Description

Full text: We have studied the effects of Ce and Y dopping in Ca-site of Ca2MnReO6 double perovskite up to 10% and 15% respectively. The Rietveld refinement of X-ray diffraction pattern showed a change in the lattice parameters of the doped without change in the space group P21/n. The X-ray Absorption Near Edge (XANES) spectra at the Mn K-edge and the Re L3-edge showed a non-integer valence for Mn and Re in all samples. The Mn average valence was +2.3. It was invariant for all samples. The Re average valence decrease with the Y content. Taken into account that the Mn average valence was invariant for all samples, the frustration temperature shift was associated with the values for Re average valence. (author)

Part of:
Proceedings of the 24th RAU: annual users meeting LNLS/CNPEM. Book of abstracts

Additional details

Publishing Information

Imprint Title
Proceedings of the 24. RAU: annual users meeting LNLS/CNPEM. Book of abstracts
Imprint Pagination
115 p.
Journal Page Range
p. 55
Report number
INIS-BR--45555

Conference

Title
annual users meeting LNLS/CNPEM
Acronym
24. RAU
Dates
11-12 Mar 2014
Place
Campinas, SP (Brazil)

INIS

Country of Publication
Brazil
Country of Input or Organization
Brazil
INIS RN
54010095
Subject category
S36: MATERIALS SCIENCE;
Resource subtype / Literary indicator
Conference
Descriptors DEI
ABSORPTION SPECTROSCOPY; DATA; DOPED MATERIALS; LATTICE PARAMETERS; PEROVSKITE; SPACE GROUPS; VALENCE; X-RAY SPECTROSCOPY
Descriptors DEC
INFORMATION; MATERIALS; MINERALS; OXIDE MINERALS; PEROVSKITES; SPECTROSCOPY; SYMMETRY GROUPS

Optional Information

Notes
Presented in abstract form only. The full text is entered in this record