Published June 1, 2014 | Version v1
Journal article

Electrochemical behavior of LiFePO4 cathode materials in the presence of anion adsorbents

  • 1. University of Chinese Academy of Sciences, Beijing 100049 (China)
  • 2. State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun 130022 (China)
  • 3. Faculty of Enginnering, Yamagata University, Jyonan 4-3-16, Yonezawa 992-8510 (Japan)
  • 4. Changzhou Institute of Enery Storage Materials and Devices, 9 Hehai Eastern Road, Changzhou 213000 (China)

Description

The poor rate capability is a major problem of olivine-structured lithium iron phosphate (LFP) cathode material in lithium-ion batteries due to its low electric conductivity and sluggish lithium diffusion. Other than the custom strategies to solve this problem like carbon coating and nano-size treatment, we simply mixed LFP with some anion adsorbents, which can store anions from the electrolytes swiftly. The effect of anion adsorbents on the performance of LFP composite electrode has been investigated by cyclic voltammetric tests and the corresponding apparent lithium diffusion coefficients have been measured

Availability note (English)

Available from http://dx.doi.org/10.1016/j.electacta.2014.03.050

Additional details

Identifiers

DOI
10.1016/j.electacta.2014.03.050;
PII
S0013-4686(14)00561-1;

Publishing Information

Journal Title
Electrochimica Acta
Journal Volume
130
Journal Page Range
p. 532-536
ISSN
0013-4686
CODEN
ELCAAV

Optional Information

Copyright
Copyright (c) 2014 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.