Taming the escape dynamics of nonadiabatic time-periodically driven quantum dissipative system within the frame of Wigner formalism
- 1. Department of Chemistry, Bengal Engineering and Science University, Shibpur, Howrah 711103 (India)
- 2. Department of Physics, Katwa College, Katwa, Burdwan 713130 (India)
Description
Highlights: • Nonadiabatic dynamics of quantum particle under the impact of high-frequency force. • Formulation of time-independent dynamics via Floquet and Kapitza schemes. • Manipulation of external force parameters allows us to control the escape rate. • Increase of (amplitudes/frequency) causes the system to decay faster, in general. • Crossover temperature increases in the presence of the field. - Abstract: Escape under the action of the external modulation constitutes a nontrivial generalization of an conventional Kramers rate because the system is away from thermal equilibrium. A derivation of this result from the point of view of Langevin dynamics in the frame of Floquet theorem in conjunction with the Kapitza–Landau time window (that leads to an attractive description of the time-dependent quantum dynamics in terms of time-independent one) has been provided. The quantum escape rate in the intermediate-to-high and very-high damping regime so obtained analytically using the phase space formalism associated with the Wigner distribution and path-integral formalism bears a quantum correction that depends strongly on the barrier height. It is shown that an increase of (amplitude/frequency) ratio causes the system to decay faster, in general. The crossover temperature between tunneling and thermal activation increases in the presence of field so that quantum effects in the escape are relevant at higher temperatures
Availability note (English)
Available from http://dx.doi.org/10.1016/j.chemphys.2014.01.008Additional details
Identifiers
- DOI
- 10.1016/j.chemphys.2014.01.008;
- PII
- S0301-0104(14)00018-4;
Publishing Information
- Journal Title
- Chemical Physics
- Journal Volume
- 431-432
- Journal Page Range
- p. 26-38
- ISSN
- 0301-0104
- CODEN
- CMPHC2
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 46124916
- Subject category
- S71: CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS;
- Descriptors DEI
- CORRECTIONS; DAMPING; DIFFUSION BARRIERS; MODULATION; PARTICLES; PATH INTEGRALS; PERIODICITY; PHASE SPACE; QUANTUM MECHANICS; TAMOXIFEN; THERMAL EQUILIBRIUM; TIME DEPENDENCE; TUNNEL EFFECT; WIGNER DISTRIBUTION
- Descriptors DEC
- EQUILIBRIUM; INTEGRALS; MATHEMATICAL SPACE; MECHANICS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; SPACE; VARIATIONS
Optional Information
- Copyright
- Copyright (c) 2014 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.