Published February 2004 | Version v1
Journal article Metadata-only

Formation of dibenzenevanadium in the reaction of dysprosium diiodide with vanadocene in benzene

Creators

  • 1. RAN, Inst. Metalloorganicheskoj Khimii im. G.A. Razuvaeva, Nizhnij Novgorod (Russian Federation)

Description

It was ascertained that heating of dysprosium diiodide with vanadocene in benzene at 85 deg C in the course of 10 h results in formation of dibenzoylvanadium (1). Compound 1 was isolated from solution with a 15% yield as a result of sublimation in vacuum at a temperature of 110 deg C, being characterized by data of ESR spectra and by melting point

Abstract (Russian)

Установлено, что нагревание дииодида диспрозия с ванадоценом в бензоле при 85 град С в течение 10 ч приводит к образованию дибензолванадия (1). Соединение 1 было выделено из раствора с выходом 15% в результате возгонки в вакууме при температуре 110 град С и охарактеризовано данными ЭПР спектров и по температуре плавления

Additional details

Additional titles

Original title (Russian)
Образование дибензолванадия в результате реакции дииодида диспрозия c ванадоценом в бензоле

Publishing Information

Journal Title
Izvestiya Akademii Nauk. Rossijskaya Akademiya Nauk. Seriya Khimicheskaya
Journal Issue
no.2
Journal Page Range
p. 459
ISSN
1026-3500
CODEN
IASKEA

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
37046443
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
BENZENE; CHEMICAL PREPARATION; CHEMICAL REACTION YIELD; ELECTRON SPIN RESONANCE; MELTING POINTS; SPECTRA; VANADIUM COMPLEXES
Descriptors DEC
AROMATICS; COMPLEXES; HYDROCARBONS; MAGNETIC RESONANCE; ORGANIC COMPOUNDS; PHYSICAL PROPERTIES; RESONANCE; SYNTHESIS; THERMODYNAMIC PROPERTIES; TRANSITION ELEMENT COMPLEXES; TRANSITION TEMPERATURE; YIELDS

Optional Information

Notes
3 refs.