Published July 2018
| Version v1
Journal article
Synthesis and structural features of new pentacoordinated monofluorosilanes containing C,O-chelate ligands based on 2-amino acid N-methylamides
Creators
- 1. N. I. Pirogov Russian National Research Medical University (Russian Federation)
Description
Pentacoordinated monofluorosilanes R1SO2NHCHR2C(O)N(Me)CH2SiMe2F containing moieties of N′-methyl-N-(organosulfonyl)-2-amino acid amides of glycine, alanine, and leucine as C,O-chelating ligands were synthesized via the reaction of corresponding disiloxanes with BF3•Et2O. The structures of obtained compounds were investigated by single-crystal X-ray diffraction analysis.
Additional details
Identifiers
Publishing Information
- Journal Title
- Russian Chemical Bulletin
- Journal Volume
- 67
- Journal Issue
- 7
- Journal Page Range
- p. 1299-1306
- ISSN
- 1066-5285
- CODEN
- RCBUEY
INIS
- Country of Publication
- United States
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 51025186
- Subject category
- S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ALANINES; AMIDES; BORON FLUORIDES; CHELATES; CHELATING AGENTS; GLYCINE; LEUCINE; LIGANDS; MONOCRYSTALS; SILICON; SILICON COMPOUNDS; SYNTHESIS; X-RAY DIFFRACTION
- Descriptors DEC
- AMINO ACIDS; BORON COMPOUNDS; BORON HALIDES; CARBOXYLIC ACIDS; COHERENT SCATTERING; COMPLEXES; CRYSTALS; DIFFRACTION; ELEMENTS; FLUORIDES; FLUORINE COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; ORGANIC ACIDS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; SCATTERING; SEMIMETALS
Optional Information
- Copyright
- Copyright (c) 2018 Springer Science+Business Media, LLC, part of Springer Nature