Published October 1995 | Version v1
Journal article

Thorium(IV) complexes of triazene-1-oxides

  • 1. R.D. and D.J. College, Munger (India). P.G. Dept. of Chemistry
  • 2. K.S.S. College, Lakhisarai (India)
  • 3. Model Inter College, Munger (India)

Description

Thorium(IV) complexes of monobasic bidentate triazene-1-oxides are reported. The complexes invariably show coordination number eight. The stereochemistry assigned is dimorphic distorted square antiprism on the basis of similar IR band positions of tetrakis (triazene-1-oxidato) thorium(IV) with [Th(acac)4]. The complexes reported have been found remarkably volatile and sublime near 100 degC (10-3 torr) without decomposition. (author). 10 refs., 2 tabs

Additional details

Publishing Information

Journal Title
Asian Journal of Chemistry
Journal Volume
7
Journal Issue
4
Journal Page Range
p. 869-872.
ISSN
0970-7077
CODEN
AJCHEW