Published 2002
| Version v1
Miscellaneous
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Flow technique study of ion/molecule reactions of CH2OH+ and CH3CHOH+ ions with ethanol at 1 Torr He pressure
Creators
- 1. Institute of Energy Problems of Chemical Physics, Russian Academy of Science, Leminsky Prospect 38, bldg. 2, Moscow (Russian Federation)
Description
A reaction of XE+ ion with ethanol and subsequent transformations of the product ions were studied. A kinetic scheme describing the evolution of the ionic composition has been determined. The rate constants of the key reactions involved in the scheme have been evaluated. A competition of a low exoergic charge transfer with an association process was detected. The competition takes place due to a long lifetime of the collisional complex with respect to a reactive and reverse decay. A model describing an evolution of the collisional complex has been suggested. (author)
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33060800.pdf
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Additional details
Publishing Information
- Imprint Title
- SASP. Contributions to the 13. Symposium on atomic and surface physics and related topics
- Imprint Pagination
- 353 p.
- Journal Page Range
- p. 336-339
- Report number
- INIS-AT--0030
Conference
- Title
- 13. Symposium on atomic and surface physics and related topics (SASP)
- Dates
- 17-23 Feb 2002
- Place
- Kitzbuehel (Austria)
INIS
- Country of Publication
- Austria
- Country of Input or Organization
- Austria
- INIS RN
- 33060800
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS;
- Resource subtype / Literary indicator
- Conference
- Descriptors DEI
- ACETALDEHYDE; ADDUCTS; CATIONS; DIMERS; DISSOCIATION; ELECTRON TRANSFER; ETHANOL; FORMALDEHYDE; ION PAIRS; ION-MOLECULE COLLISIONS; IONIC COMPOSITION; REACTION KINETICS; RELAXATION; THRESHOLD ENERGY; TRANSFER REACTIONS; XENON IONS
- Descriptors DEC
- ALCOHOLS; ALDEHYDES; CHARGED PARTICLES; COLLISIONS; DIRECT REACTIONS; ENERGY; HYDROXY COMPOUNDS; ION COLLISIONS; IONS; KINETICS; MOLECULE COLLISIONS; NUCLEAR REACTIONS; ORGANIC COMPOUNDS