Published 2024 | Version v1
Journal article

Assessment of certain theoretical modeling for extraction data of uranium ion by loaded SM-7 with TBP using fixed bed column operation

  • 1. Analytical Chemistry Department, Hot Laboratories Center, Egyptian Atomic Energy Authority, Cairo (Egypt)
  • 2. Chemistry of Nuclear Fuel Department, Hot Laboratories Center, Egyptian Atomic Energy Authority, Cairo (Egypt)

Description

Theoretical evaluation of experimental extraction data of U (VI) from nitric acid solutions by tri-n-butyl phosphate (TBP) loaded on macro reticular polymer SM-7 was verified using Thomas and Yan models. These data are represented by breakthrough relations at different conditions; flow rate, concentrations and interfering ions. Comparing correlation coefficients (R2) of both models, it was found that R2 equal 0.96 for Thomas model comparing to 0.88 for Yan one, indicating that Thomas model is convenient for evaluation of that extraction process. The calculated, theoretically, value of (qTh) was found to be almost equal to (qexp) the practical one.

Availability note (English)

Available from: http://dx.doi.org/10.1515/ract-2024-0293

Additional details

Identifiers

Publishing Information

Journal Title
Radiochimica Acta
Journal Volume
112
Journal Issue
12
Journal Page Range
p. 947-953
ISSN
0033-8230
CODEN
RAACAP