Published 2024
| Version v1
Journal article
Assessment of certain theoretical modeling for extraction data of uranium ion by loaded SM-7 with TBP using fixed bed column operation
- 1. Analytical Chemistry Department, Hot Laboratories Center, Egyptian Atomic Energy Authority, Cairo (Egypt)
- 2. Chemistry of Nuclear Fuel Department, Hot Laboratories Center, Egyptian Atomic Energy Authority, Cairo (Egypt)
Description
Theoretical evaluation of experimental extraction data of U (VI) from nitric acid solutions by tri-n-butyl phosphate (TBP) loaded on macro reticular polymer SM-7 was verified using Thomas and Yan models. These data are represented by breakthrough relations at different conditions; flow rate, concentrations and interfering ions. Comparing correlation coefficients (R) of both models, it was found that R equal 0.96 for Thomas model comparing to 0.88 for Yan one, indicating that Thomas model is convenient for evaluation of that extraction process. The calculated, theoretically, value of (q) was found to be almost equal to (q) the practical one.
Availability note (English)
Available from: http://dx.doi.org/10.1515/ract-2024-0293Additional details
Identifiers
Publishing Information
- Journal Title
- Radiochimica Acta
- Journal Volume
- 112
- Journal Issue
- 12
- Journal Page Range
- p. 947-953
- ISSN
- 0033-8230
- CODEN
- RAACAP
INIS
- Country of Publication
- Germany
- Country of Input or Organization
- Germany
- INIS RN
- 56009067
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- AQUEOUS SOLUTIONS; COMPARATIVE EVALUATIONS; COMPUTERIZED SIMULATION; CONCENTRATION RATIO; EXTRACTION; EXTRACTION CHROMATOGRAPHY; EXTRACTION COLUMNS; FLOW RATE; NITRIC ACID; PACKED BEDS; POLYMERS; RADIOCHEMISTRY; TBP; URANIUM IONS
- Descriptors DEC
- BUTYL PHOSPHATES; CHARGED PARTICLES; CHEMISTRY; CHROMATOGRAPHY; DIMENSIONLESS NUMBERS; DISPERSIONS; EQUIPMENT; ESTERS; EVALUATION; EXTRACTION APPARATUSES; HOMOGENEOUS MIXTURES; HYDROGEN COMPOUNDS; INORGANIC ACIDS; INORGANIC COMPOUNDS; IONS; MIXTURES; NITROGEN COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC PHOSPHORUS COMPOUNDS; OXYGEN COMPOUNDS; PHOSPHORIC ACID ESTERS; SEPARATION EQUIPMENT; SEPARATION PROCESSES; SIMULATION; SOLUTIONS