Published May 15, 1975 | Version v1
Report

A molecular beam electric resonance study of the hyperfine Λ-doubling spectrum of OH, OD, SH and SD, ch. 6

  • 1. Katholieke Universiteit Nijmegen (Netherlands). Afdeling Experimentele Natuurkunde

Description

The molecular beam electric resonance method was employed to obtain a complete set of hyperfine Λ-doubling transitions of the free radicals OH, OD, SH and SD. The observed spectra could very well be explained by the degenerate perturbation theory adapted to the 2PI state. The experimental results include fine and hyperfine coupling constants and the electric dipole moments for all four molecules and some magnetic properties of SH. The deduced hyperfine coupling constants agree well with the ab-initio calculations

Additional details

Publishing Information

Imprint Title
Properties of diatomic open-shell molecules by the molecular-beam electric-resonance spectroscopy
Imprint Pagination
p. 79-132.
Report number
INIS-mf--1979

INIS

Country of Publication
Netherlands
Country of Input or Organization
Netherlands
INIS RN
7225925
Subject category
S74: ATOMIC AND MOLECULAR PHYSICS;
Resource subtype / Literary indicator
Thesis
Descriptors DEI
BEAM PRODUCTION; DEUTERIUM COMPOUNDS; ELECTRIC DIPOLE MOMENTS; ELECTRIC RESONANCE; ENERGY-LEVEL TRANSITIONS; FINE STRUCTURE; HYDROXYL RADICALS; HYPERFINE STRUCTURE; MOLECULAR BEAMS; PERTURBATION THEORY; ROTATION; STARK EFFECT
Descriptors DEC
BEAMS; DIPOLE MOMENTS; ELECTRIC MOMENTS; HYDROGEN COMPOUNDS; RADICALS; RESONANCE

Optional Information

Notes
Also published in Canadian Journal of Physics, v. 53(17) p. 2123-2141 (Oct 1975).