Fabrication of chitin nanofiber-PDMS composite aerogels from Pickering emulsion templates with potential application in hydrophobic organic contaminant removal

Highlights: • ChNF-PDMS aerogels were fabricated from a Pickering emulsion template. • The aerogels with wrinkling patterns showed homogeneous hydrophobicity. • The introduction of PDMS enhanced the mechanical resilience of the aerogels. • Removal of CCl₄ droplets and aqueous trichloroethylene from water was achieved. • The aerogesl could be regenerated by mechanical squeezing for over 20 recycles. Natural polymers have aroused increasing attention in water treatment but their application in removing hydrophobic organic contaminants (HOCs) was limited due to their hydrophilicity. Herein, hydrophobic aerogels were successfully fabricated from Pickering emulsions stabilized by chitin nanofibers (ChNF) with polydimethylsiloxane (PDMS) as dispersed phase and glutaraldehyde as a crosslinking agent, and their performance in HOCs removal were evaluated. The Pickering emulsions with PDMS ratios of 2.5–20% v/v showed high stability, demonstrating great potential as aerogel templates. The solidified PDMS droplets were evenly distributed within the matrix, contributing to homogeneous and permanent hydrophobicity. The composite aerogels with water contact angles of over 130° could selectively remove non-aqueous phase HOCs from water. The CCl₄ adsorption capacity was 521–2820 wt%, depending on PDMS contents. Meanwhile, the mechanical resilience of the composite aerogels was significantly improved, facilitating the adsorbent regeneration by simple mechanical squeezing. The adsorption capacity remained above 85% for 24 cycles. Moreover, the aerogels could also remove dissolved HOCs from water with a maximum adsorption capacity of 1.34 mg/g for 10 mg/L TCE. This work reveals the potential of Pickering emulsions in the fabrication of composite hydrophobic materials from natural biopolymers with promising application in HOCs related water treatment.