Published February 2000 | Version v1
Journal article Metadata-only

A new Zintl phase Sn1.9Cu4.7P22I8 with a structure of the clathrate-1: directional synthesis and structure

Creators

  • 1. Moskovskij Gosudarstvennyj Univ. im. M.V. Lomonosova, Khimicheskij Fakul'tet, Moscow (Russian Federation)

Description

New tin-copper phosphideiodide Sn19.3Cu4.7P22I8 (I) is obtained as a result of the two-stage pulse synthesis carried out on the basis of its composition forecast with application of the Zintl electron calculation scheme. The crystal structure I is determined by the data of monocrystal roentgenodiffraction experiment. The compound I is crystallized by the clathrate-I-type in cubic syngony, sp. gr. Pm3-bar n, a = 10.847(1) A, Z = 4. Three-dimensional framework, built-up of tin, copper and phosphorus atoms, wherein large hollows of two types are occupied by iodide atoms constitutes the basis of the structure. All phosphorus positions in I are completely occupied in contrast to the Sn24P19.3I8

Abstract (Russian)

Новый фосфидиодид олова-меди Sn19.3Cu4.7P22I8 (I) получен в результате двухстадийного импульсного синтеза, проведенного на основе предсказания его состава с использованием схемы электронного подсчета Цинтля. Кристаллическая структура I определена по данным монокристаллического рентгенодиффракционного эксперимента. Соединение I кристаллизуется по типу клатрата-I в кубической сингонии, пр. гр. Pm3-bar n, a = 10.847(1) A, Z = 4. Основу структуры составляет трехмерный каркас, построенный из атомов олова, меди и фосфора, в котором большие пустоты двух типов занимают атомы иода. Все позиции атомов фосфора в I полностью заселены в отличие от структуры Sn24P19.3I8

Additional details

Additional titles

Original title (Russian)
Новая фаза Цинтля Сн

Publishing Information

Journal Title
Zhurnal Neorganicheskoj Khimii
Journal Volume
45
Journal Issue
2
Journal Page Range
p. 203-209
ISSN
0044-457X
CODEN
ZNOKAQ

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
31035806
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
BOND ANGLE; BOND LENGTHS; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; COPPER IODIDES; CUBIC LATTICES; ELECTRONIC STRUCTURE; LATTICE PARAMETERS; MONOCRYSTALS; PHOSPHORUS IODIDES; SPACE GROUPS; TIN IODIDES
Descriptors DEC
COPPER COMPOUNDS; COPPER HALIDES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; CRYSTALS; DIMENSIONS; HALIDES; HALOGEN COMPOUNDS; IODIDES; IODINE COMPOUNDS; LENGTH; PHOSPHORUS COMPOUNDS; SYMMETRY GROUPS; SYNTHESIS; TIN COMPOUNDS; TIN HALIDES; TRANSITION ELEMENT COMPOUNDS

Optional Information

Notes
23 refs., 3 figs., 4 tabs.