Published January 4, 1978 | Version v1
Journal article Metadata-only

Absolute rates of hydrogen abstraction by tert-butoxy radicals

Creators

  • 1. Univ. of Notre Dame, IN

Description

The reaction of tert-butoxy radicals with diphenylmethanol and with cumene was examined using nanosecond laser flash photolysis techniques in order to determine the absolute values of the rates of reaction of the radicals. The absolute rate measured for both substrates compare favorably with the values for the benzophenone triplet

Additional details

Identifiers

DOI
10.1021/ja00469a058;

Publishing Information

Journal Title
Journal of the American Chemical Society
Journal Volume
100
Journal Issue
1
Series
J. Am. Chem. Soc.
Journal Page Range
296-298
ISSN
0002-7863

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
9378403
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Resource subtype / Literary indicator
No Abstract
Descriptors DEI
ALCOHOLS; BUTOXY RADICALS; CHEMICAL REACTION KINETICS; CUMENE; PHOTOLYSIS
Descriptors DEC
ALKOXY RADICALS; AROMATICS; CHEMICAL REACTIONS; DECOMPOSITION; HYDROCARBONS; HYDROXY COMPOUNDS; KINETICS; ORGANIC COMPOUNDS; RADICALS; REACTION KINETICS

Optional Information

Notes
Published in summary form only.; Updated automatically by Metadata and Full-Text Enrichment Agent