Published December 2007
| Version v1
Journal article
Mechanochemistry of the 5f-element compounds. Part 2. Mechanochemically induced change in coordination mode of UO2(CH3COO)2 x 2H2O
- 1. Sofia University, Sofia (Bulgaria). Faculty of Chemistry
- 2. Bulgarian Academy of Sciences, Sofia (Bulgaria). Institute of General and Inorganic Chemistry
Description
The effect of the mechanical treatment of UO2(CH3COO)2 x 2H2O in a planetary ball mill in air or as a suspension in toluene or benzene on its crystal structure and coordination mode has been studied. No significant changes in the crystal structure are observed. IR-spectroscopy results suggest that in the part of the mechanoactivated material the bidentate bonding of the CH3COO- is transformed in monodentate one. The newformed species is soluble in non-polar solvents. (author)
Additional details
Publishing Information
- Journal Title
- Journal of Radioanalytical and Nuclear Chemistry
- Journal Volume
- 274
- Journal Issue
- 3
- Journal Page Range
- p. 465-471
- ISSN
- 0236-5731
- CODEN
- JRNCDM
INIS
- Country of Publication
- Hungary
- Country of Input or Organization
- Hungary
- INIS RN
- 39020551
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- CRYSTAL STRUCTURE; MECHANICAL PROPERTIES; ORGANIC COMPOUNDS; RADIOCHEMISTRY; SOLUBILITY; URANIUM COMPOUNDS
- Descriptors DEC
- ACTINIDE COMPOUNDS; CHEMISTRY
Optional Information
- Notes
- 15 refs.