Qualification of FFA treatment for the water-steam cycle as an innovative lay-up strategy for the long term outage of a CANDU-6 reactor

The majority of worldwide operating Nuclear Power Plants is older than 25 years, which is accompanied with extended outage duration due to large refurbishment and upgrade programs, e.g. Steam Generator Replacement and other large component replacement. For these long term outages adequate and cost effective preservation methods are required. Normally during outages, systems and components are drained and opened to atmosphere whereas wet surfaces and moisture condensation can result in uniform corrosion of carbon steel and eventually other materials; superimposed localized corrosion is possible in presence of impurities. For those systems there are in general two different lay-up methods possible. Dry lay-up by removing all water and humidity from the components or wet lay-up with demineralized and oxygen free water and additional corrosion inhibitors. Disadvantages of these lay-up methods are: High man power and hardware efforts for performing dry lay-up. Usage of hazardous chemicals like Hydrazine. Insufficient results of both lay-up methods in case of switching between dry and wet lay-up. To improve the lay-up concept for long term outages, AREVA GmbH developed an innovative concept using FFA (Film-Forming Amines) for secondary side system lay-up. The entire water-steam cycle including the Steam Generators is treated in one step without any negative impact on the treated structural materials. This technology has been applied for the first time at NPP Embalse. Embalse Nuclear Power Station consists of a CANDU-6 reactor of 648 MWe electrical output. It is in commercial operation since 1984. The shutdown for refurbishment and preparation for the second cycle of operation that includes among other tasks the replacement of the existing steam generators and power uprating has been scheduled for 2014, which causes the necessity of a lay-up optimization in the plant. This paper deals in detail with the qualification process of the FFA treatment considering the specifics of this plant. This work has been carried out by the refurbishment group and plant operator personnel (Central Nuclear Embalse, N.A.S.A.), AREVA GmbH and CNEA experts to implement the FFA treatment before steam generator replacement. (author)