Published December 2004 | Version v1
Journal article

57Fe Moessbauer Spectroscopic Study on the Assembled Iron Complexes

  • 1. Hiroshima University, Natural Science Center for Basic Research and Development (N-BARD) (Japan)
  • 2. Hiroshima University, Department of Chemistry, Graduate School of Science (Japan)

Description

57Fe Moessbauer spectroscopy was carried out to know the electronic states of the assembled iron complexes. The IS value revealed a high-spin FeII state in the bipyridine and pyrazine iron complexes with NCS or NCSe. The dissociation behavior of ligand was investigated by TG, and the resultant change in the coordination sphere around iron atom was reflected in the change in QS value.

Additional details

Publishing Information

Journal Title
Hyperfine Interactions
Journal Volume
156-157
Journal Issue
1-4
Journal Page Range
p. 353-358
ISSN
0304-3843
CODEN
HYINDN

Conference

Title
27. international conference on the applications of the Moessbauer Effect
Acronym
ICAME 2003
Dates
21-25 Sep 2003
Place
Muscat (Oman)

INIS

Country of Publication
Netherlands
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
43027888
Subject category
S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
Resource subtype / Literary indicator
Conference
Descriptors DEI
ATOMS; BIPYRIDINES; DISSOCIATION; IRON 57; IRON COMPLEXES; LIGANDS; MOESSBAUER EFFECT; PYRAZINES; SPIN
Descriptors DEC
ANGULAR MOMENTUM; AZINES; COMPLEXES; EVEN-ODD NUCLEI; HETEROCYCLIC COMPOUNDS; INTERMEDIATE MASS NUCLEI; IRON ISOTOPES; ISOTOPES; NUCLEI; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; PARTICLE PROPERTIES; PYRIDINES; STABLE ISOTOPES; TRANSITION ELEMENT COMPLEXES

Optional Information

Copyright
Copyright (c) 2004 Kluwer Academic Publishers