Published September 2000 | Version v1
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Synthesis, molecular and crystal structure of K4.5[(MO3(μ3-Te)(μ2-Te)3(CN)6)I]I1.5x3H2O and Cs3[(Mo3(μ3-Te)(μ2-Te2)3(CN)6)I]x2H2O

Creators

Description

Crystal structure of two new compounds containing triangular tellurium-bridge cluster fragments (Mo3(μ3-Te)(μ2-Te2)34+, i.e. K4.5[(Mo3(μ3-Te)(μ2-Te2)3(CN)6)I]I1.5x3H2O: sp.gr. P3c1, Z = 4, a = 13.280(1), c = 23.800(3) A and Cs3[(Mo3(μ3-Te)(μ2-Te2)3(CN)6)I]x2H2O: sp.gr. P21/n, Zn = 2, a = 9.650(2), b = 22.297(5), c = 27.446(7) A, β = 94.10 (2) were studied by the method of X-ray diffraction analysis. It was ascertained that ionic pairs [(Mo3Te7(CN)6)I]3- with Teax...I distances 3.358-3.676 A are formed in both compounds. he structure of the cesium salt is of ionic type with inclusion of H2O molecules and anion packing according to the double-layer close packing law

Abstract (Russian)

Методом рентгеноструктурного анализа исследованы кристаллические структуры двух новых соединений, содержащих треугольные теллуромостиковые кластерные фрагменты (Mo3(μ3-Te)(μ2-Te2)34+, K4.5[(Mo3(μ3-Te)(μ2-Te2)3(CN)6)I]I1.5x3H2O: пр.гр. P3c1, Z = 4, a = 13,280(1), c = 23,800(3) A , Cs3[(Mo3(μ3-Te)(μ2-Te2)3(CN)6)I]x2H2O: пр.гр. P21/n, Zn = 2, a = 9,650(2), b = 22,297(5), c = 27,446(7) A, β = 94,10 (2). Установлено, что в обоих соединениях образуются ионные пары [(Mo3Te7(CN)6)I]3- с расстояниями Teах...I 3,358-3,676 A. Структура цезиевой соли - ионного типа с включением молекул Н2О и укладкой анионов по закону двухслойной плотнейшей упаковки

Additional details

Additional titles

Original title (Russian)
Синтез, молекулярная и кристаллическая структура К

Publishing Information

Journal Title
Zhurnal Strukturnoj Khimii
Journal Volume
41
Journal Issue
5
Journal Page Range
p. 1027-1035
ISSN
0136-7463
CODEN
ZSTKAI

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
32053993
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
BOND ANGLE; BOND LENGTHS; CESIUM COMPOUNDS; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; CRYSTAL LATTICES; CYANIDES; HYDRATES; INTERATOMIC DISTANCES; IODIDES; LATTICE PARAMETERS; MOLECULAR STRUCTURE; MOLYBDENUM COMPLEXES; POTASSIUM COMPOUNDS; TELLURIDES; X-RAY DIFFRACTION
Descriptors DEC
ALKALI METAL COMPOUNDS; CHALCOGENIDES; COHERENT SCATTERING; COMPLEXES; CRYSTAL STRUCTURE; DIFFRACTION; DIMENSIONS; DISTANCE; HALIDES; HALOGEN COMPOUNDS; IODINE COMPOUNDS; LENGTH; SCATTERING; SYNTHESIS; TELLURIUM COMPOUNDS; TRANSITION ELEMENT COMPLEXES

Optional Information

Notes
13 refs.; 4 tabs.; 3 figs.