Published 2016 | Version v1
Journal article Metadata-only

Synthesis, structure and electronic configuration of [Rh6Te8(PPh3)6].4C6H6

Creators

  • 1. Marburg Univ. (Germany). Fachbereich Chemie
  • 2. Marburg Univ. (Germany). Fachbereich Chemie and Wissenschaftliches Zentrum fuer Materialwissenschaften

Description

[Rh6Te8(PPh3)6].4C6H6, the first compound with a molecular Chevrel-type [Rh6Te8] cluster core has been synthesized and structurally characterized. By means of quantum chemical calculation, the close relationship of its electronic configuration to that of the lighter homologue has been demonstrated. The different crystal solvent content prevents an isostructural crystallization.

Additional details

Publishing Information

Journal Title
Zeitschrift fuer Naturforschung. B: Chemical Sciences
Journal Volume
71
Journal Issue
5
Series
Special issue: Dedicated to Professor Wolfgang Jeitschko on the occasion of his 80"t"h birthday
Journal Page Range
p. 391-394
ISSN
0932-0776
CODEN
ZNBSEN

INIS

Country of Publication
Germany
Country of Input or Organization
Germany
INIS RN
47080546
Subject category
S36: MATERIALS SCIENCE;
Descriptors DEI
CRYSTAL STRUCTURE; MOLECULAR STRUCTURE; RHODIUM COMPOUNDS; SYNTHESIS; TELLURIUM COMPOUNDS
Descriptors DEC
REFRACTORY METAL COMPOUNDS; TRANSITION ELEMENT COMPOUNDS