Size-Spectra and growth of particles bearing As, Se, Sb, and Zn in Washington, Dc, area aerosol by instrumental neutron activation analysis

Aerosol particles smaller than 1.8 μm were size-fractionated with micro-orifice impactors at two urban sites near Washington, DC, and analyzed for 44 elements including, As, Se, Sb, and Zn, i.e., elements strongly associated with coal combustion, incineration, and regionally transported secondary aerosol, by Instrumental Neutron Activation. Size distribution parameters were determined nonparametrically and with a least-squares peak-fitting method using impactor calibration data. Geometric and fitted mass mean aerodynamic diameters typically differed by < 10% and increased continuously with increasing relative humidity (RH) in the range 56 to 79%, but along different curves for samples influenced by local and distant sources. The geometric mass mean diameters for samples influenced by winds from the direction of local sources were uniformly smaller than those influenced by westerly winds bearing aerosol from distant, regional, sources. At 60% RH, gmmads were As, 0.30 ± 0.03 and 0.46 ± 0.04; Se, 0.33 ± 0.06 and 0.54 ± 0.04; Sb, 0.39 ± 0.03 and 0.53 ± 0.04; and Zn, 0.39 ± 0.06 and 0.53 ± 0.08; respectively. (author) 28 refs.; 2 figs.; 2 tabs