Published 1994 | Version v1
Journal article Metadata-only

Electron diffraction study of the structure of NbOCl3 molecule

Creators

  • 1. Ivanovskij Gosudarstvennyj Univ., Ivanovo (Russian Federation)

Description

A simultaneous X-ray diffraction and mass spectrometric study of niobium oxytrichloride molecule is performed. Conditions are determined which ensure the presence of the only molecular species, NbOCl3, in vapour phase. Structural parameters of the molecule corresponding to the C3V configuration are as follows: r?Nb=O)=1.682(6)A; r(Nb-Cl)=2.276(5)A; (O-Nb-Cl) angle = 107.5 (0.5)0. 9 refs., 2 figs., 4 tabs

Additional details

Additional titles

Original title (Russian)
Жлектронографическое исследование строения молекулы NbOCl

Publishing Information

Journal Title
Izvestiya Vysshikh Uchebnykh Zavedenij, Khimiya i Khimicheskaya Tekhnologiya
Journal Volume
37
Journal Issue
10-12
Journal Page Range
p. 57-62.
ISSN
0579-2991
CODEN
IVUKAR

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
28066674
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
BOND ANGLE; BOND LENGTHS; ELECTRON DIFFRACTION; MASS SPECTROSCOPY; MOLECULAR STRUCTURE; MOLECULES; NIOBIUM COMPOUNDS; OXYCHLORIDES
Descriptors DEC
CHLORINE COMPOUNDS; COHERENT SCATTERING; DIFFRACTION; HALOGEN COMPOUNDS; OXYGEN COMPOUNDS; OXYHALIDES; SCATTERING; SPECTROSCOPY; TRANSITION ELEMENT COMPOUNDS