Published 2011
| Version v1
Journal article
Synthesis and characterization of a linker for primary amines used in the solid phase organic synthesis of spermidine
Creators
- 1. Universidade Federal do Rio de Janeiro (IQ/UFRJ), RJ (Brazil). Inst. de Quimica
- 2. Aix-Marseille Univ., Marseille (France). Campus de Saint Jerome
- 3. Aix-Marseille Universite Spectropole - Federation de Sciences Chimiques de Marseille, Campus de Saint Jerome (France)
Description
A linker resin for the synthesis of functionalized spermidine in good yield is described, along with its characterization by infrared (IR), 13C solid-state nuclear magnetic resonance with cross polarization and magic angle spinning (13C CPMAS NMR) and 1H high resolution magic angle spinning nuclear magnetic resonance (1H HRMAS NMR). This linker has been regenerated after cleavage of spermidine and re-used without loss of efficiency. (author)
Availability note (English)
Available from http://www.scielo.br/pdf/jbchs/v22n1/11.pdfAdditional details
Identifiers
Publishing Information
- Journal Title
- Journal of the Brazilian Chemical Society
- Journal Volume
- 22
- Journal Issue
- 1
- Journal Page Range
- p. 86-91
- ISSN
- 0103-5053
- CODEN
- JOCSET
INIS
- Country of Publication
- Brazil
- Country of Input or Organization
- Brazil
- INIS RN
- 42034204
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ACETONITRILE; BARBITURATES; CARBON 13; CLEAVAGE; HYDROGEN 1; INFRARED SPECTRA; ISOPROPYL RADICALS; NMR SPECTRA; PYRIDINE; SPERMIDINE
- Descriptors DEC
- ALKYL RADICALS; AMINES; ANESTHETICS; AZINES; CARBON ISOTOPES; CENTRAL NERVOUS SYSTEM AGENTS; CENTRAL NERVOUS SYSTEM DEPRESSANTS; DRUGS; EVEN-ODD NUCLEI; HETEROCYCLIC COMPOUNDS; HYDROGEN ISOTOPES; HYPNOTICS AND SEDATIVES; ISOTOPES; LIGHT NUCLEI; MICROSTRUCTURE; NITRILES; NUCLEI; ODD-EVEN NUCLEI; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; PYRIDINES; PYRIMIDINES; RADICALS; SPECTRA; STABLE ISOTOPES