Published January 1979 | Version v1
Journal article Metadata-only

Radiation-chemical synthesis of alkyl adamantanes with fluorinated side chain

Creators

  • 1. Nauchno-Issledovatel'skij Fiziko-Khimicheskij Inst., Moscow (USSR)

Description

Studied is radiation-chemical alkylation of adamantane by hexafluoropropylene in the liquid phase using a solvent at the effect of Co60 γ-radiation. Effect of various parameters on the reaction rate is studied. Alkylation product accumulation kinetics is taken. A possible mechanism of reactions is discussed. All the products synthesized for the first time are separated in a pure form and identified. Their physico-chemical constants are presented

Additional details

Additional titles

Original title (Russian)
Радиационно-химический синтез фторированных в боковую цепь алкиладамантанов

Publishing Information

Journal Title
Khim. Vys. Ehnerg.
Journal Volume
13
Journal Issue
1
Series
Khim. Vys. Ehnerg.
Journal Page Range
27-33
ISSN
0023-1193

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
10468962
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Descriptors DEI
ALKENES; ALKYLATION; CHEMICAL PREPARATION; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTION KINETICS; CYCLOALKANES; GAMMA RADIATION; LIQUIDS; ORGANIC FLUORINE COMPOUNDS
Descriptors DEC
ALKANES; CHEMICAL REACTIONS; ELECTROMAGNETIC RADIATION; FLUIDS; HYDROCARBONS; IONIZING RADIATIONS; KINETICS; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; RADIATION EFFECTS; RADIATIONS; REACTION KINETICS; SYNTHESIS

Optional Information

Notes
For English translation see the journal High Energy Chem.