Applications of AMS to hydrology

The evaluation and management of water as a resource requires an understanding of the chemical, and geological interactions that water effects or undergoes in the hydrologic cycle. Delivery of water to the land surface by precipitation, subsequent streamflow, circulation in surface waters and evapotranspiration, infiltration, recharge, movement of waters in the subsurface, and discharge are of interest. Also important are the quality of water, water's role in mineral dissolution, transport, and deposition, and the various water-related geotechnical problems of subsidence, tectonics, slope instability, and earth structures. Mathematical modeling techniques are available and are being improved which describe these phenomena and predict future system behavior. Typically, however, models suffer from substantial uncertainties due to insufficient data. Refinement, calibration,and verification of hydrologic models require expansion of the data base. Examination of chemical constituents of water which act as tracers can often supply the needed information. Unfortunately, few tracers are available which are both mobile and chemically stable. Several long-lived radioisotopic hydrologic tracers exist, however, which have received little attention in hydrologic studies to date because of low concentration, low specific activity, or sample size limitations. Recent development of ultra-sensitive accelerator mass spectrometry techniques (AMS) by Purser and others (1977), Nelson and others (1977), Bennett and others (1978), Muller and others (1978), Raisbeck and others (1978) is now expected to provide access to many of these tracers