Published May 2010 | Version v1
Journal article Metadata-only

Hydrothermal synthesis and 121Sb Moessbauer characterization of perovskite-type oxides: Ba2SbLnO6 (Ln = Pr, Nd, Sm, Eu)

Creators

  • 1. Department of Materials Chemistry, College of Chemistry, Nankai University, Tianjin 300071 (China)
  • 2. Department of Physics, Nanjing University, Nanjing 210093 (China)

Description

A mild hydrothermal process to prepare Ba2SbLnO6 (Ln = Pr, Nd, Sm, Eu) perovskite-type oxides are presented. These perovskites were characterized on the basis of X-ray diffraction (XRD), X-ray photoelectron spectra (XPS), inductively-coupled plasma spectra (ICP) techniques. Primary structure was confirmed using Rietveld method based on XRD data shows that the likely space groups of Ba2SbLnO6 are R-3 for Ln = Pr and Nd and Fm-3m for Ln = Sm and Eu, respectively. The measurement of Moessbauer effect of the 37.2 keV γ transition of 121Sb indicates that the isomer shift of these perovskites falls in the region of the Sb5+ and reflects some hybridized-orbital behavior in Sb-O bonds.

Availability note (English)

Available from http://dx.doi.org/10.1016/j.matchar.2010.02.012

Additional details

Identifiers

DOI
10.1016/j.matchar.2010.02.012;
PII
S1044-5803(10)00043-4;

Publishing Information

Journal Title
Materials Characterization
Journal Volume
61
Journal Issue
5
Journal Page Range
p. 548-553
ISSN
1044-5803
CODEN
MACHEX

INIS

Country of Publication
United States
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
44025527
Subject category
S36: MATERIALS SCIENCE;
Descriptors DEI
ABSORPTION SPECTRA; ANTIMONY 121; BARIUM COMPOUNDS; CHEMICAL BONDS; EUROPIUM OXIDES; ISOMER SHIFT; MOESSBAUER EFFECT; NEODYMIUM OXIDES; PEROVSKITE; PRASEODYMIUM OXIDES; SAMARIUM OXIDES; X-RAY DIFFRACTION; X-RAY PHOTOELECTRON SPECTROSCOPY
Descriptors DEC
ALKALINE EARTH METAL COMPOUNDS; ANTIMONY ISOTOPES; CHALCOGENIDES; COHERENT SCATTERING; DIFFRACTION; ELECTRON SPECTROSCOPY; EUROPIUM COMPOUNDS; INTERMEDIATE MASS NUCLEI; ISOTOPES; MINERALS; NEODYMIUM COMPOUNDS; NUCLEI; ODD-EVEN NUCLEI; OXIDE MINERALS; OXIDES; OXYGEN COMPOUNDS; PEROVSKITES; PHOTOELECTRON SPECTROSCOPY; PRASEODYMIUM COMPOUNDS; RARE EARTH COMPOUNDS; SAMARIUM COMPOUNDS; SCATTERING; SPECTRA; SPECTROSCOPY; STABLE ISOTOPES

Optional Information

Copyright
Copyright (c) 2010 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.