Published November 1985 | Version v1
Report Metadata-only

Autoionization resonances observed in the photoionization efficiency spectra of HgX2+, X = Cl, Br, and I, and their fragments

Creators

  • 1. Ames Lab., IA

Description

The comparison of the photoionization efficiency (PIE) spectrum for Hg+ from Hg and those for HgX2+, X = Cl, Br, and I, shows that prominent autoionization Rydberg series observed in the PIE spectra for these mercury dihalide and their fragment ions can be assigned to transitions, which are mainly associated with the mercury atom in HgX2. Autoionization resonances observed in different fragment ion channels are found to exhibit different Beutler-Fano line profiles. An attempt was made to fit the autoionization resonance profiles using the Fano line shape formula. 21 references, 4 figures, 5 tables

Additional details

Publishing Information

Imprint Title
Proceedings of the workshop on some aspects of autoionization in atoms and small molecules
Journal Page Range
p. 155-174.
Report number
ANL-PHY--85-3

Conference

Title
Workshop on autoionization of atoms and small molecules.
Dates
2-3 May 1985.
Place
Argonne, IL (USA).

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
17063442
Subject category
S74: ATOMIC AND MOLECULAR PHYSICS;
Resource subtype / Literary indicator
Conference, Numerical Data
Descriptors DEI
AUTOIONIZATION; CATIONS; ELECTRON EMISSION; ELECTRON SPECTROSCOPY; EXPERIMENTAL DATA; LINE WIDTHS; MEETINGS; MERCURY BROMIDES; MERCURY CHLORIDES; MERCURY IODIDES; MOLECULES; RESONANCE ABSORPTION; RYDBERG STATES; SPECTRA; US DOE
Descriptors DEC
ABSORPTION; BROMIDES; BROMINE COMPOUNDS; CHARGED PARTICLES; CHLORIDES; CHLORINE COMPOUNDS; DATA; EMISSION; ENERGY LEVELS; EXCITED STATES; HALIDES; HALOGEN COMPOUNDS; INFORMATION; IODIDES; IODINE COMPOUNDS; IONIZATION; IONS; MERCURY COMPOUNDS; NATIONAL ORGANIZATIONS; NUMERICAL DATA; SPECTROSCOPY; US ORGANIZATIONS