Population of individual Ne 1s-1np Rydberg states measured across the 1s ionization threshold and the evolution of shake-up into shake-down

New high-resolution experimental results on Ne 1s near-threshold photoionization with subsequent decay into a 2p4(1D2)n'p or 2p4(1D2)ε'p state are presented. The population of Rydberg states up to n'=12 is determined as a function of excess energy. These data allow one to track in detail the transition from resonant Auger decay going along with shake-up of the spectator electron to shake-down and photoionization with recapture of the photoelectron. Results are in good agreement with a time-dependent quantum mechanical theory of Auger decay in the presence of a slow photoelectron