Published February 1993 | Version v1
Journal article Metadata-only

Rhenium(5) and molybdenum(5) complexes with 4',4(5)-divaleryldibenzo-18-crown-6

Creators

  • 1. Tadzhikskij Gosudarstvennyj Univ., Dushanbe (Tajikistan)

Description

Methods for synthesizing oxohalide complexes of rhenium and molybdenum with +5 oxidation degree with 4',4(5)-divaleryldibenzo-18-crown-6 were developed. Content and composition of prepared compounds were investigated by the methods of element analysis, crystal optics, conductometry, IR spectroscopy in the near and far regions, thermogravimetry. Oxidation degree of the complex-forming metal was determined. It was established that composition of the compounds coressponded to the general formula MOLX · H2O, where M - Re, Mo; L -4',4(5)-divaleryldibenzo-18-crown-6; X -Cl-, Br-

Additional details

Additional titles

Original title (Russian)
Комплексные соединения рения(5) и молибдена(5) с 4',4

Publishing Information

Journal Title
Zhurnal Neorganicheskoj Khimii
Journal Volume
38
Journal Issue
2
Journal Page Range
p. 278-282.
ISSN
0044-457X
CODEN
ZNOKAQ

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
24074079
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CHEMICAL PREPARATION; CHEMICAL REACTION YIELD; CROWN ETHERS; ELECTRIC CONDUCTIVITY; INFRARED SPECTRA; MOLECULAR STRUCTURE; MOLYBDENUM COMPLEXES; OXYHALIDES; RHENIUM COMPLEXES; SOLUTIONS; VALENCE
Descriptors DEC
COMPLEXES; DISPERSIONS; ELECTRICAL PROPERTIES; ETHERS; HALOGEN COMPOUNDS; HOMOGENEOUS MIXTURES; MIXTURES; ORGANIC COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; SPECTRA; SYNTHESIS; TRANSITION ELEMENT COMPLEXES; YIELDS