Published June 2016 | Version v1
Journal article

Densities of unloaded and CO2-loaded 3-dimethylamino-1-propanol at temperatures (293.15 to 343.15) K

  • 1. Faculty of Technology, University College of Southeast Norway, Kjølnes Ring 56, Porsgrunn 3918 (Norway)
  • 2. Tel-Tek, Kjølnes Ring 30, Porsgrunn 3918 (Norway)

Description

Highlights: • Densities of 3-dimethylamino-1-propanol solutions were measured at different mass fractions and temperatures up to 343.15 K. • Excess molar volumes for unloaded solutions were correlated using Redlich–Kister method. • Experimental density data for CO2-loaded solutions were correlated using Weiland method. - Abstract: This article reports experimental density values of aqueous 3-dimethylamino-1-propanol (3DMA1P) solutions over the entire range of 3DMA1P mass fractions and temperatures of (293.15 to 343.15) K. Based on the experimental results, corresponding values of thermal expansion and excess molar volume of 3DMA1P solutions were established. A second order Redlich–Kister polynomial equation satisfactorily correlates excess molar volumes against mole fractions of 3DMA1P solutions, and regression of these parameters as a function of temperature is demonstrated. Densities of carbonated 3DMA1P solutions were also measured at three 3DMA1P mass fractions of 0.20, 0.30 and 0.50, at different CO2-loadings up to 0.8 mol CO2/mol 3DMA1P, and temperatures. These data were modeled. A comparison between experimental and calculated values are discussed.

Availability note (English)

Available from http://dx.doi.org/10.1016/j.jct.2016.02.007

Additional details

Identifiers

DOI
10.1016/j.jct.2016.02.007;
PII
S0021-9614(16)00057-4;

Publishing Information

Journal Title
Journal of Chemical Thermodynamics
Journal Volume
97
Journal Page Range
p. 282-289
ISSN
0021-9614
CODEN
JCTDAF

Optional Information

Copyright
Copyright (c) 2016 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.