Published September 14, 2006 | Version v1
Journal article

Vibrationally resolved partial cross sections and asymmetry parameters for oxygen K-shell photoionization of the CO2 molecule

  • 1. Department of Physics, Sophia University, Tokyo 102-8554 (Japan)
  • 2. Japan Synchrotron Radiation Research Institute, Sayo-gun, Hyogo 679-5198, Japan (Japan)
  • 3. Institute of Physics, St Petersburg State University, 198504 St Petersburg, Russia (Russian Federation)
  • 4. Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Sendai 980-8577 (Japan)

Description

O K-shell photoionization of the CO2 molecule causes antisymmetric vibrations v3' in the core-ionized molecule. The v3'-resolved partial cross sections σ+v3' and asymmetry parameters βv3' are measured in the Σu shape resonance region above the O K-shell ionization threshold of the CO2 molecule. Neither the shape resonance energy in σ+v3' nor the value of βv3' shows v3'-dependence. This v3'-independent nature is attributed to the fact that v3' vibrations do not cause any change of the size of the potential box responsible for the formation of the shape resonance. Multiple scattering calculations employing the v3'-dependent fixed-nuclei approximation reproduce well the measured v3'-resolved partial cross sections

Availability note (English)

Available online at http://stacks.iop.org/0953-4075/39/3655/b6_17_021.pdf or at the Web site for the Journal of Physics. B, Atomic, Molecular and Optical Physics (ISSN 1361-6455) http://www.iop.org/

Additional details

Publishing Information

Journal Title
Journal of Physics. B, Atomic, Molecular and Optical Physics
Journal Volume
39
Journal Issue
17
Journal Page Range
p. 3655-3663
ISSN
0953-4075
CODEN
JPAPEH

INIS

Country of Publication
United Kingdom
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
38014593
Subject category
S74: ATOMIC AND MOLECULAR PHYSICS;
Descriptors DEI
APPROXIMATIONS; ASYMMETRY; CARBON DIOXIDE; CROSS SECTIONS; K SHELL; MOLECULES; MULTIPLE SCATTERING; NUCLEI; OXYGEN; PHOTOIONIZATION; POTENTIALS; RESONANCE
Descriptors DEC
CALCULATION METHODS; CARBON COMPOUNDS; CARBON OXIDES; CHALCOGENIDES; ELECTRONIC STRUCTURE; ELEMENTS; IONIZATION; NONMETALS; OXIDES; OXYGEN COMPOUNDS; SCATTERING