Published January 1, 2012 | Version v1
Journal article

Applications of metal hydride-based bipolar electrodes

  • 1. Gas Technology Institute, 1700 S. Mount Prospect Road, Des Plaines, IL 60018 (United States)
  • 2. Inter American University of Puerto Rico, Bayamon, PR 00957 (United States)
  • 3. UTC Power, 195 Governor's Highway, South Windsor, CT 06074 (United States)
  • 4. Department of Chemistry and Chemical Biology, Northeastern University, Boston, MA 02115 (United States)

Description

Metal hydride foils can serve as support structures for electronically insulating proton conductors to afford metal hydride-barrier composite electrolytes operating at temperatures in between molten carbonate fuel cells and phosphoric acid fuel cells. In addition, such barrier electrolytes entirely decouple anode and cathode reactant streams and water management, enabling general analytical methods that separate electrode kinetic from reactant crossover effects. This strategy was exemplified with a direct methanol fuel cell catalyzed with PtRu. No fuel-stream reactant or product crossover other than protons was detected.

Availability note (English)

Available from http://dx.doi.org/10.1016/j.electacta.2011.11.002

Additional details

Identifiers

DOI
10.1016/j.electacta.2011.11.002;
PII
S0013-4686(11)01653-7;

Publishing Information

Journal Title
Electrochimica Acta
Journal Volume
59
Journal Page Range
p. 470-473
ISSN
0013-4686
CODEN
ELCAAV

Optional Information

Copyright
Copyright (c) 2011 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.