Published July 1994 | Version v1
Journal article Metadata-only

Crystal structure of complex neptunium(5) molybdate Na2[(NpO2)2(MoO4)2H2O]xH2O

Creators

  • 1. AN SSSR, Moscow (Russian Federation). Inst. Kosmicheskikh Issledovanij
  • 2. AN SSSR, Moscow (Russian Federation). Inst. Fizicheskoj Khimii

Description

Crystal structure of the complex in the title has been studied, crystallographic data being ascertained: a = 9.004(2), b = 10.980(2), c 13.229(2) A, β = 102.46(2(, V = 1277.0(8)A, sp.gr. P21/n, Z = 4 d(calcd) = 4.89 g/cm3. The complex structure is of the frame type. Coordination polyhedrons of both independent Np atoms are pentagonal bipyramids joined by a common edge. MoO4 groups are tridentate - and tetradentated-bridge ones. 16 refs.; 2 figs.; 2 tabs

Additional details

Additional titles

Original title (Russian)
Кристаллическая структура комплексного молибдата нептуния (5) На

Publishing Information

Journal Title
Koordinatsionnaya Khimiya
Journal Volume
20
Journal Issue
7
Journal Page Range
p. 552-556.
ISSN
0132-344X
CODEN
KOKHDC

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
27010110
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY; S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CRYSTAL LATTICES; DENSITY; HYDRATES; LATTICE PARAMETERS; MOLYBDATES; NEPTUNIUM COMPLEXES; SODIUM COMPOUNDS; SPACE GROUPS
Descriptors DEC
ACTINIDE COMPLEXES; ALKALI METAL COMPOUNDS; COMPLEXES; CRYSTAL STRUCTURE; MOLYBDENUM COMPOUNDS; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; SYMMETRY GROUPS; TRANSITION ELEMENT COMPOUNDS; TRANSURANIUM COMPLEXES