Published November 1, 2016 | Version v1
Journal article

Experimental measurements of Stark widths for Mn I lines in long laser spark

  • 1. Department of Chemistry, Lomonosov Moscow State University, 119234, Leninskie Gory, Moscow (Russian Federation)
  • 2. Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, 119991, Kosygina, 19, Moscow (Russian Federation)

Description

We report the experimental Stark widths of Mn I lines belonging to multiplets z6P° → a6S and z6D° → a6D in long spark induced by laser. We have used aluminum alloy containing 80 ppm of manganese as a target to avoid strong self-absorption of Mn I lines. Its absence was proved by the comparison of observed intensities with relative strengths of lines within multiplets. Electron density of plasma estimated by Mg I (5172.68 Å) and Al II (2816.18 Å) lines was within the range of (4–30) × 1016 cm−3. The shortest possible gate allowed the observation of symmetric atomic and ionic lines. The spatial profiles of plasma temperature and electron density along the axis of long spark demonstrated that both values were lower than for spherical plasma. Measured Stark widths of resonance multiplet z6P° → a6S decrease from 0.075 Å for its first component to 0.055 Å for the last one, while Stark widths of components of multiplet z6D° → a6D increase from 0.095 Å to 0.125 Å. No Stark shifting was observed for the studied multiplets. - Highlights: • Diagnostics of long laser-induced plasma • Stark widths of resonance and non-resonance Mn I lines • No Stark shifts are observed.

Availability note (English)

Available from http://dx.doi.org/10.1016/j.sab.2016.09.014

Additional details

Identifiers

DOI
10.1016/j.sab.2016.09.014;
PII
S0584-8547(16)30224-5;

Publishing Information

Journal Title
Spectrochimica Acta. Part B, Atomic Spectroscopy
Journal Volume
125
Journal Page Range
p. 43-51
ISSN
0584-8547
CODEN
SAASBH

INIS

Country of Publication
Netherlands
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
49102975
Subject category
S36: MATERIALS SCIENCE;
Descriptors DEI
ALUMINIUM ALLOYS; ELECTRON DENSITY; ELECTRON TEMPERATURE; LASERS; MANGANESE; PLASMA DIAGNOSTICS; SELF-ABSORPTION
Descriptors DEC
ABSORPTION; ALLOYS; ELEMENTS; METALS; SORPTION; TRANSITION ELEMENTS

Optional Information

Copyright
Copyright (c) 2016 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.