Published 1991 | Version v1
Journal article Metadata-only

Effects of electrochemical reduction of uranyl complexes in propylene carbonate

Creators

  • 1. Strasbourg-1 Univ., 67 (France)
  • 2. Ecole Europeenne des Hautes Etudes des Industries Chimiques de Strasbourg (France)

Description

The electrochemical reduction of uranyl/acyl-4-pyrazolone-5 complexes, involving several substituent groups on the pyrazolone, was carried out on a mercury electrode, using propylene carbonate as solvent. The analysis of the redox behaviour of a set of three complexes illustrated that stable reduced uranium complexes were obtained from U(VI) complexes through direct electrolysis. (author)

Additional details

Additional titles

Original title (French)
Effets de substituants sur la reduction electrochimique de complexes d'uranyle dans le carbonate de propylene

Publishing Information

Journal Title
Electrochimica Acta
Journal Volume
36
Journal Issue
2
Series
Electrochim. Acta.
Journal Page Range
325-331
ISSN
0013-4686
CODEN
ELCAA

INIS

Country of Publication
United Kingdom
Country of Input or Organization
United Kingdom
INIS RN
22036674
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ELECTROCHEMISTRY; ELECTROLYSIS; PYRAZOLES; REDOX POTENTIAL; REDUCTION; URANIUM COMPLEXES; URANYL COMPLEXES; VOLTAMETRY
Descriptors DEC
ACTINIDE COMPLEXES; AZOLES; CHEMICAL REACTIONS; COMPLEXES; HETEROCYCLIC COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS