Published December 1, 1976 | Version v1
Journal article Metadata-only

Pulse radiolytic formation of Na- from alkali metal - sodium ion solutions in ethylamine

Creators

  • 1. Atomic Energy of Canada Ltd., Chalk River, Ontario. Chalk River Nuclear Labs.

Description

The formation of Na- from K, Rb, Cs, or Li ethylamide solutions containing small amounts of Na+ has been observed by pulse radiolysis. In K, Rb, or Cs solutions evidence is presented which shows that the production of Na- occurs via the corresponding alkali anions K-, Rb-, or Cs-. However solutions containing Li behave much differently and indicate that Na+ is 'complexed' or associated with Li+ ions. Probable reaction mechanisms are discussed. (author)

Additional details

Identifiers

DOI
10.1139/v76-528;

Publishing Information

Journal Title
Canadian Journal of Chemistry
Journal Volume
54
Journal Issue
23
Series
Can. J. Chem.
Journal Page Range
3672-3676
ISSN
0008-4042

INIS

Country of Publication
Canada
Country of Input or Organization
Canada
INIS RN
8298475
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Descriptors DEI
ABSORPTION SPECTRA; ALKALI METAL COMPOUNDS; AMINES; ANIONS; CHEMICAL REACTION KINETICS; ELECTRON BEAMS; EQUILIBRIUM; PULSED IRRADIATION; RADIOLYSIS; SODIUM; SODIUM COMPLEXES; SODIUM COMPOUNDS; SOLUTIONS
Descriptors DEC
ALKALI METAL COMPLEXES; ALKALI METALS; BEAMS; CHARGED PARTICLES; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; COMPLEXES; DECOMPOSITION; DISPERSIONS; ELEMENTS; HOMOGENEOUS MIXTURES; IONS; IRRADIATION; KINETICS; LEPTON BEAMS; METALS; MIXTURES; ORGANIC COMPOUNDS; PARTICLE BEAMS; RADIATION EFFECTS; REACTION KINETICS; SPECTRA

Optional Information

Notes
20 refs.; Updated automatically by Metadata and Full-Text Enrichment Agent