Published January 2005
| Version v1
Journal article
Syntheses, structures and third-order non-linear optical properties of homometal clusters containing molybdenum
Creators
- 1. College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, No. 119 JieFang Road, Changchun, Jilin 130023 (China)
- 2. Fujian Institute of Research on the Structure of Matter, Chinese Academy of Science, Fuzhou 350002 (China)
- 3. College of Physics, Jilin University, Changchun, Jilin 130023 (China)
Description
Both the homometal cluster [P(ph4)]2[Mo2O2(μ-S)2(S2)2] (1) and [Mo2O2(μ-S)2(Et2dtc)2] (2) (Et2dtc=diethyl-dithiocarbamate) were successfully synthesized by low-temperature solid-state reactions. X-ray single-crystal diffraction studies suggest that compound (1) is a dinuclear anion cluster, and compound (2) is a dinuclear neutral cluster. The two compounds were characterized by elemental analyses, IR spectra and UV-Vis spectra. The third-order non-linear optical (NLO) properties of the clusters were also investigated and all exhibited nice non-linear absorption and self-defocusing performance with moduli of the hyperpolarizabilities 5.145x10-30esu for (1) and 5.428x10-30esu for (2)
Additional details
Identifiers
- DOI
- 10.1016/j.jssc.2004.11.004;
- PII
- S0022-4596(04)00601-2;
Publishing Information
- Journal Title
- Journal of Solid State Chemistry
- Journal Volume
- 178
- Journal Issue
- 1
- Journal Page Range
- p. 363-369
- ISSN
- 0022-4596
- CODEN
- JSSCBI
INIS
- Country of Publication
- United States
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 37034207
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ABSORPTION; INFRARED SPECTRA; MOLYBDENUM; MOLYBDENUM COMPLEXES; MONOCRYSTALS; OPTICAL PROPERTIES; SOLID CLUSTERS; SYNTHESIS; ULTRAVIOLET SPECTRA; VISIBLE SPECTRA; X-RAY DIFFRACTION
- Descriptors DEC
- COHERENT SCATTERING; COMPLEXES; CRYSTALS; DIFFRACTION; ELEMENTS; METALS; PHYSICAL PROPERTIES; REFRACTORY METALS; SCATTERING; SORPTION; SPECTRA; TRANSITION ELEMENT COMPLEXES; TRANSITION ELEMENTS
Optional Information
- Copyright
- Copyright (c) 2005 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.