Change of adsorption/desorption of cesium on illite depending on the ionic strength of ion exchange electrolyte
- 1. Decommissioning Technology Research Division, Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)
- 2. Dept. of Chemical Engineering and Applied Chemistry, Chungnam National University, Daejeon (Korea, Republic of)
Description
Frayed edge sites are formed by weathering llite, which is highly selective for Cs. In this study, it was collapsed due to K+ in the interlayer, so that other cation exchange ions were hardly adsorbed and other cation exchange electrolyte were adsorbed on illite because Cs desorption was difficult. In other words, we intend to confirm the adsorption / desorption and structural change of Cs by Ca2+, Na+, K+ adsorption, Ca2+ with high hydration energy and de-collapse between layers through ion exchange electrolyte at high concentration and increase CEC capacity. We have experimented to changes of adsorption and desorption depending on Na+, K+, Ca2+ ionic strength. It was considered that one of the reasons why the concentration used for desorption of Cs was fixed at a low concentration of 3mM and could not be changed. Fortunately, we have found a good desorption effect on oxlic acid in 2:1 nonexpandable clay
Additional details
Publishing Information
- Publisher
- KRS
- Imprint Place
- Daejeon (Korea, Republic of)
- Imprint Title
- Proceedings of the Conference and Symposium Korean Radioactive Waste Society Spring Meeting 2018
- Imprint Pagination
- 426 p.
- Journal Page Range
- p. 309-310
Conference
- Title
- 2018 Spring Meeting of Korean Radioactive Waste Society
- Dates
- 30 Mar 2018
- Place
- Daejeon (Korea, Republic of)
INIS
- Country of Publication
- Korea, Republic of
- Country of Input or Organization
- Korea, Republic of
- INIS RN
- 50066697
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Resource subtype / Literary indicator
- Conference, Non-conventional Literature
- Descriptors DEI
- ADSORPTION; CESIUM; CLAYS; DESORPTION; ELECTROLYTES; HYDRATION; ION EXCHANGE; SURFACES
- Descriptors DEC
- ALKALI METALS; ELEMENTS; METALS; MINERALS; SILICATE MINERALS; SOLVATION; SORPTION
Optional Information
- Notes
- 2 figs