Published March 2018 | Version v1
Miscellaneous

Change of adsorption/desorption of cesium on illite depending on the ionic strength of ion exchange electrolyte

  • 1. Decommissioning Technology Research Division, Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)
  • 2. Dept. of Chemical Engineering and Applied Chemistry, Chungnam National University, Daejeon (Korea, Republic of)

Description

Frayed edge sites are formed by weathering llite, which is highly selective for Cs. In this study, it was collapsed due to K+ in the interlayer, so that other cation exchange ions were hardly adsorbed and other cation exchange electrolyte were adsorbed on illite because Cs desorption was difficult. In other words, we intend to confirm the adsorption / desorption and structural change of Cs by Ca2+, Na+, K+ adsorption, Ca2+ with high hydration energy and de-collapse between layers through ion exchange electrolyte at high concentration and increase CEC capacity. We have experimented to changes of adsorption and desorption depending on Na+, K+, Ca2+ ionic strength. It was considered that one of the reasons why the concentration used for desorption of Cs was fixed at a low concentration of 3mM and could not be changed. Fortunately, we have found a good desorption effect on oxlic acid in 2:1 nonexpandable clay

Part of:
Proceedings of the Conference and Symposium Korean Radioactive Waste Society Spring Meeting 2018

Additional details

Publishing Information

Publisher
KRS
Imprint Place
Daejeon (Korea, Republic of)
Imprint Title
Proceedings of the Conference and Symposium Korean Radioactive Waste Society Spring Meeting 2018
Imprint Pagination
426 p.
Journal Page Range
p. 309-310

Conference

Title
2018 Spring Meeting of Korean Radioactive Waste Society
Dates
30 Mar 2018
Place
Daejeon (Korea, Republic of)

INIS

Country of Publication
Korea, Republic of
Country of Input or Organization
Korea, Republic of
INIS RN
50066697
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Resource subtype / Literary indicator
Conference, Non-conventional Literature
Descriptors DEI
ADSORPTION; CESIUM; CLAYS; DESORPTION; ELECTROLYTES; HYDRATION; ION EXCHANGE; SURFACES
Descriptors DEC
ALKALI METALS; ELEMENTS; METALS; MINERALS; SILICATE MINERALS; SOLVATION; SORPTION

Optional Information

Notes
2 figs