Published January 1982
| Version v1
Journal article
The mercury-photosensitized decomposition of hexamethyldisilane
Creators
- 1. Max-Planck-Institut fuer Kohlenforschung, Muelheim an der Ruhr (Germany, F.R.). Inst. fuer Strahlenchemie
Description
The kinetics and mechanism of the mercury-photosensitized decomposition of hexamethyldisilane have been studied. It has been confirmed that the initially-formed radica, Me3SiSi(Me2)CH2, undergoes a unimolecular rearrangment; Arrhenius parameters have been measured for this rearrangement and for subsequent reactions of the rearranged radical. The significance of these Arrhenius parameters in silicon chemistry is discussed by means of thermochemical calculations. (orig./RDE)
Additional details
Publishing Information
- Journal Title
- Ber. Bunsenges. Phys. Chem.
- Journal Volume
- 86
- Journal Issue
- 1
- Series
- CODEN: BBPCA.;Ber. Bunsenges. Phys. Chem.
- Journal Page Range
- 13-19
- ISSN
- 0005-9021
INIS
- Country of Publication
- Germany
- Country of Input or Organization
- Germany
- INIS RN
- 15012618
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY; S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ARRHENIUS EQUATION; CHEMICAL REACTION KINETICS; COMPARATIVE EVALUATIONS; DECOMPOSITION; HIGH TEMPERATURE; LOW TEMPERATURE; MERCURY; PHOTOCHEMISTRY; PHOTOSENSITIVITY; RADICALS; SILANES
- Descriptors DEC
- CHEMICAL REACTIONS; CHEMISTRY; ELEMENTS; HYDRIDES; HYDROGEN COMPOUNDS; KINETICS; METALS; REACTION KINETICS; SENSITIVITY; SILICON COMPOUNDS