Published May 1, 1980 | Version v1
Journal article

Exact quantum, quasiclassical forward and reverse reaction probabilities for a collinear asymmetric model reaction

  • 1. Paris-11 Univ., 91 - Orsay (France). Lab. de Chimie Theorique

Description

Detailed quasiclassical and time-independent quantum reaction probabilities are given for a surface on which large discrepancies between quasiclassical and wavepacket results have previously been found. The quasiclassical results are shown to agree relatively resonably with the oscillation-averaged time-independent quantum ones if the quasiclassical reverse probabilities are chosen in the threshold region. (orig.)

Additional details

Publishing Information

Journal Title
Chem. Phys. Lett.
Journal Volume
71
Journal Issue
3
Series
Chem. Phys. Lett.
Journal Page Range
519-523
ISSN
0009-2614

Conference

Title
6. international conference on molecular energy transfer.
Dates
16 - 20 Jul 1979.
Place
Rodez, France.

INIS

Country of Publication
Netherlands
Country of Input or Organization
Netherlands
INIS RN
12597392
Subject category
S74: ATOMIC AND MOLECULAR PHYSICS;
Resource subtype / Literary indicator
Conference
Descriptors DEI
ATOM-MOLECULE COLLISIONS; CHEMICAL REACTION KINETICS; EXCITED STATES; MATHEMATICAL MODELS; PROBABILITY; QUANTUM MECHANICS
Descriptors DEC
ATOM COLLISIONS; COLLISIONS; ENERGY LEVELS; KINETICS; MECHANICS; MOLECULE COLLISIONS; REACTION KINETICS