Published May 2004 | Version v1
Journal article Metadata-only

EPR study of interactions in the MoOCl3 - diethyl dithiophosphate - diethylamine system

Creators

  • 1. RAN, Inst. Obshchej i Neorganicheskoj Khimii im. N.S. Kurnakova, Moscow (Russian Federation)

Description

By the method of EPR in MoOCl3-DDFH-DEta system when reagents ration is 1:1:>3 formation of a new molybdenum(V) imidocomplex in situ solution is detected. Composition and structure of a new molybdenum(V) imidocomplex - composition is MoNRCl(DDF)3(DDFH), coordination number is 7, structure is pentagonal bipyramid - are determined using analysis of additional superfine structure from atoms of ligands forming coordination sphere of molybdenum(V) imidocomplex

Abstract (Russian)

Методом ЭПР в системе MoOCl3-DDFH-DEta при соотношении реагентов 1:1:>3 зафиксировано образование в растворе in situ нового имидокомплекса молибдена(V). На основании анализа дополнительной сверхтонкой структуры от атомов лигандов, образующих координационную сферу атома молибдена, установлены состав и строение нового имидокомплекса молибдена(V): состав MoNRCl(DDF)3(DDFH), КЧ=7 и строение пентагональной бипирамиды

Additional details

Additional titles

Original title (Russian)
Исследование методом EhPR взаимодействий в системе MoOCl

Publishing Information

Journal Title
Zhurnal Neorganicheskoj Khimii
Journal Volume
49
Journal Issue
5
Journal Page Range
p. 830-836
ISSN
0044-457X
CODEN
ZNOKAQ

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
35092242
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CHEMICAL COMPOSITION; CHEMICAL PREPARATION; CHEMICAL REACTION KINETICS; CONCENTRATION RATIO; COORDINATION NUMBER; IMIDES; MOLECULAR STRUCTURE; MOLYBDENUM COMPLEXES; ORGANIC PHOSPHORUS COMPOUNDS; ORGANIC SULFUR COMPOUNDS
Descriptors DEC
COMPLEXES; KINETICS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; REACTION KINETICS; SYNTHESIS; TRANSITION ELEMENT COMPLEXES

Optional Information

Notes
14 refs.; 1 tab.; 2 figs.